Unit 1 Flashcards

1
Q

Ionisation energy

A

Energy required to pull one mole of electrons away from one mole of gaseous atoms

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2
Q

Electronegativity

A

Atom which has a strong attraction for bonding is said to be highly electronegative

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3
Q

Collision theory says that a chemical reaction takes place when

A

Molecules have sufficient energy known as the Ea

Molecules collide with the correct geometry

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4
Q

The number of collisions is affected by

A

Concentration
Particle size
Pressure

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5
Q

Activation energy is affected by

A

Temperature

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6
Q

How does increasing the temperature affect the reaction rate

A

More particles will have the minimum energy and therefore more reactions will take place

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7
Q

What is activation energy

A

Ea

Sufficient energy for a reaction to take place

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8
Q

Catalysts increase reaction rate by

A

Allowing the reaction to take place via an alternative route that has a lower activation energy

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9
Q

Two types of catalyst

A

Heterogeneous- different state from substrate

Homogeneous- same state

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10
Q

How to measure relative rate

A

RR=1/time taken for reaction

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11
Q

Enthalpy

A

Measure of chemical potential energy contained in a substance

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12
Q

Change in enthalpy =

A

Hp-Hr

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13
Q

In an exothermic reaction the products have_____ energy than the reactants

A

Less

Therefore always negative

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14
Q

In an endothermic reaction the products have_____ energy than the reactants

A

More

Therefore always positive

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15
Q

Intermolecular bonding

A

Van der waals and between different molecules eg water and water

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16
Q

Intramolecular bonding

A

Bonding within a molecule eg hydrogen and oxygen in water

17
Q

Non polar

A

Pure equal forces of attraction

18
Q

Polar

A

Slightly negative or slightly positive

19
Q

Ionic

A

Very electronegative atom takes an electron away from the other, forming an ion

20
Q

Properties of ionic

A

High melting point
Conducts electricity when molten or solution
Always solid room temp

21
Q

What to remember about solubility of substances

A

Like dissolves in like

22
Q

Covalent molecular properties

A

Any state at room temp
Lower melting point
Never conducts

23
Q

Covalent network substances

A

Carbon
Silicon
Boron

24
Q

London dispersion forces

A

Weak electrostatic attractions due to a temporary dipole forming
Can be found in everything
Only force of attraction for non polar
As number of electrons increase, strength of LDF increases

25
Q

Dipole

A

Molecules in which an unequal distribution results in one side being slightly charged

26
Q

Permanent dipole-Permanent Dipole

A

Electrostatic attractions between permanent dipoles in molecules
Only for polar
Strong

27
Q

What substances have PDPPDP

A

Aldehydes and ketones

28
Q

Hydrogen bonding

A

Occurs when hydrogen is bonded next to a highly electronegative element such as oxygen, nitrogen or fluorine
Occurs in water
very strong