Types Of Voids And Radius Ratio 15 Flashcards
Types of packing
1D
2D
3D
1D ka CN
2
In 2d how many types of packing present
- Square packing [cn. 4]
2.close packing [cn. 6]
In 2D packing efficiency can be calculated by
Area of atom/area of
Types of 3D packing
- 2D ki square packing ko 3D me : [cn 6], 52% packed…similar to pcc
- Agr 2D ki ek layer + 2D ki ek layer voids me + …….: give BCC [ 8 ]
- 2D close pack + 2D close pack in voids of 1 layer +2D close pack in voids of 2nd layer +….ABABAB TYPE [ ]…. CCP 74%
- SAME AS ABOVE ABCABCABC [ ]… FCC ,most closed packing 74%
Each voids in 2D HCP packing surrounded by how many circles
3
Types of voids
Trigonal planer
Tetrahedral
Octahedral
Cubic
Cations occupy
Anions occy
- Voids
- Lattice points
CN. Of trigonal planer voids
This void seen in 2D closed packing
[ 3]
Cation ki size kaisi hoti hai trigonal planer voids me
Small size of cation can only occupy these voids
r+/r- = 0.155-0.225
Tetragonal voids
ABAB layer of 3D form this
CN 4
Cations of larger size can fit in the voids
r+/r-= 0.225 -0.414
Octahedral voids
CN . 6
0.414-0.732
Simple cubic void
Formed when 3D= 2D square +2D square (not in voids )
r+/r-= 0.732-0.999
CN.8
Agr hum cation ka size bada Kar DE anion ke size se to kya radius ration 1 se bada ho jayega
Nhi
It is not ,andaitary that r+ is always up r- can be up when it’s size is less
Radii of Na+ is 116, And Cl- is 116
In which type of void actions present
Octahedral