Octahedral Void Or Tetrahedral Void Flashcards

1
Q

FCC KE UNAR KITNE NO. OF VOIDs PRESENT HAI

A

8 tetrahedral void

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2
Q

In fcc how many tetrahedral or octahedral voids present

A

8td
4oh

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3
Q

How many octahedral voids present in a unit cell

A

1 octahedral voids at body centa
12 at edge centre [ ye Jo edge pr laga hoga void wo share ho rha hoga 4 unit cell se to 1 unit cell me Iskandar contribution 1/ 4th hee hoga to total no. Of octahedral void has one unit cell is 3
Means 4 octahedral voids
Body centre
1x1=1
Edge centre
12x1/4=3
4Oĥ

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4
Q

In fcc
Atoms
Td
Oh

A

4 Atoms
8 T voids
4 OH voids

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5
Q

In BCC
Atoms
Td voids
Oh voids

A

2
4td
2Oh

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6
Q

In SCC
Atoma
Td voids
Oh voids

A

1
2Td
1Oh

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7
Q

NaCl is type of unit cell
Na+ occupy
Cl- occupy
CN

A

FCc unit cell
Od voids na+=4
Cl- lattice points =4
So formula Na4Cl4=NaCl
Ionic distance = a/2
CN. 6
AB type

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8
Q

ZnS ( zinc blende)
Unitcell
Zn+2
S2-
CN
Type

A

FCC
4 td voids
4
4
AB
a x root 3/4

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9
Q

CsCl
Unit cell
Cs+
Cl-
CN
Type
Internuclear distance

A

SCC
Cs+ =1 cubic void
Cl- = 1
CN = 8
AB
ax root 3/2

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10
Q

Na cl
ZnS
CsCl

A

6
4
8

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11
Q

Fluorine structure
Ca2+ f-
Caf2

A

AB2 type hai
Ca2+ present on lattice points
Anion present on voids

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12
Q

Caf2 ke arrangement kaisa hoga

A

FCC arrangement hai to
F- 8 tetrahedral voids me present haai
Aur ca2+ 4 hai jo ki lattice points pr present hai

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13
Q

Antifluorite structure
A2B type
Na2O
Na+ on voids
O2- on lattice

A

FCC
O2- = 4
Na+= 4 (tetrahedral)

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