Types of elements/periodic properties Flashcards
metals - atomic properties
left side of periodic table low effective nuclear charge - electrons not strongly held by nucleus low electronegativity low ionization energy large radius
nonmetals - atomic properties
smaller group in the upper right hand corner
high effective nuclear charge - more protons, attract electrons and pull their own electrons toward the nucleus
high electronegativity
high ionization energy
small radius
Metalloids
stair-step group between metals and non-metals
intermediate properties
metals - physical properties
soft, shiny at STP
malleable
ductile - can be drawn into thin wire
non-metals - physical properties
any phase at STP
brittle when solid
poor conductors
non-ductile
What is effective nuclear charge?
Zeff = # protons - #nonvalence e- (attraction from nucleus-replusion from valence e)
Level of attractiveness between the positively charged nucleus and the negatively charged valence electrons
valence electrons are repelled by non valence (inner shell) electrons, decreasing ENC
What is the periodic trend of effective nuclear charge?
increases from left to right
b/c #protons increases from left to right, but # non-valence electrons stays the same
increases from bottom to top due to decreasing distance from nucleus to valence shell (more shells as you go down a group)
atomic radius
distance between center of nucleus and outermost electron shell
increasing Zeff = decreasing atomic radius
increases from right to left, top to bottom
ionic radii
anions - larger radii due to increased valence electrons
cations - smaller radii due to decreased valence electrons
atomic radii decreases as ion becomes more positive
ionization energy
energy required to remove and electron
increases from left to right, bottom to top
gaps between 1st/2nd/3rd IE are greater when it causes the atom to move from a stable state
electron affinity
energy released when an electron is gained by an atom in gaseous state
highest in halogens - adding one e makes them noble gases
electronegativity
ability of an atom to pull/hog electrons in a bond
greatest for atoms with high effective nuclear charge
increases from left to right, bottom to top
FON