TRANSITION METAL COLOURS Flashcards

1
Q

Cr(III) with limited sodium hydroxide…

A

GREEN PPT

[Cr (H20)3 (OH)3]

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2
Q

Cr(III) with excess sodium hydroxide…

A

(precipitate dissolves…)

GREEN SOLUTION

[Cr (H2O)2 (OH)4]

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3
Q

Cr(III) with limited aqueous ammonia…

A

GREEN PPT

[Cr (H2O)3 (OH)3]

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4
Q

Cr(III) with excess aqueous ammonia…

A

(precipitate dissolves…)

GREEN SOLUTION

[Cr (NH3)6] 3+

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5
Q

Mn(II) in aqueous solution…

A

PALE PINK

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6
Q

Mn(II) with limited sodium hydroxide…

A

(gelatinous)

WHITE PPT

(turns brown/darkens on standing in air)

[Mn (OH)2]

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7
Q

Mn(II) with excess sodium hydroxide…

A

PPT INSOLUBLE IN EXCESS

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8
Q

Mn(II) with limited aqueous ammonia…

A

(gelatinous)

WHITE PPT

(turns brown/darkens on standing in air)

[Mn (OH)2]

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9
Q

Mn(II) with excess aqueous ammonia…

A

PPT INSOLUBLE IN EXCESS

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10
Q

Fe(II) in aqueous solution…

A

PALE GREEN/BLUE

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11
Q

Fe(II) with limited sodium hydroxide…

A

(gelatinous)

PALE GREEN PPT

(turns brown/darkens on standing in air)

[Fe (OH)2]

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12
Q

Fe(II) with excess sodium hydroxide…

A

PPT INSOLUBLE IN EXCESS

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13
Q

Fe(II) with limited aqueous ammonia…

A

(gelatinous)

PALE GREEN PPT

(turns brown/darkens on standing in air)

[Fe (OH)2]

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14
Q

Fe(II) with excess aqueous ammonia…

A

PPT INSOLUBLE IN EXCESS

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15
Q

Fe(III) in aqueous solution…

A

YELLOW

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16
Q

Fe(III) with limited sodium hydroxide…

A

RED/BROWN PPT

[Fe(H2O)3(OH)3]
[Fe2O3•xH2O]

17
Q

Fe(III) with excess sodium hydroxide…

A

PPT INSOLUBLE IN EXCESS

18
Q

Fe(III) with limited aqueous ammonia…

A

RED/BROWN PPT

[Fe(H2O)3(OH)3]
[Fe2O3•xH2O]

19
Q

Fe(III) with excess aqueous ammonia…

A

PPT INSOLUBLE IN EXCESS

20
Q

Ni(II) in aqueous solution…

A

EMERALD GREEN

21
Q

Ni(II) with limited sodium hydroxide…

A

EMERALD GREEN PPT

[Ni(OH)2]

22
Q

Ni(II) with excess sodium hydroxide…

A

PPT INSOLUBLE IN EXCESS

23
Q

Ni(II) with limited aqueous ammonia…

A

EMERALD GREEN PPT

[Ni(OH)2]

24
Q

Ni(II) with excess aqueous ammonia…

A

(precipitate dissolves…)

LAVENDER BLUE SOLUTION

[Ni(NH3)6] 2+

25
Cu(II) in aqueous solution...
BLUE
26
Cu(II) with limited sodium hydroxide...
(gelatinous) BLUE PPT [Cu(OH)2]
27
Cu(II) with excess sodium hydroxide...
PPT INSOLUBLE IN EXCESS
28
Cu(II) with limited aqueous ammonia...
(gelatinous) BLUE PPT [Cu(OH)2]
29
Cu(II) with excess ammonia...
(precipitate dissolves) DEEP BLUE SOLUTION [Cu(NH3)4(H2O)2] 2+
30
Zn...
COLOURLESS
31
Cr(III) in aqueous solution...
VIOLET