Trace elements dissolved in the ocean Flashcards

1
Q

What are the key sources of dissolved materials?

A

•Fluvial (with river water)
• Atmospheric
• Hydrothermal

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2
Q

What are the components of seawater?

A

• Major ions
• Minor constituents
• Trace elements

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3
Q

What are examples of major ions components in seawater?

A

Alkali earths and halides (especially Sodium Chloride (NaCl), bicarbonate and calcium

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4
Q

What are some minor constituents in seawater?

A

• Gases — e.g. N2, O2, CO2
• Nutrients — e.g. NO3-, PO42-, SiO2

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5
Q

What are trace elements?

A

Everything else present in the sea but not in high concentration

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6
Q

What is true of elements entering the ocean from rivers?

A

• Some elements dissolved in the water may also remain in estuaries — e.g. phosphorous may remain attached to particulate matter
• Much of the particulate load (up to 90%) is trapped in estuaries and coastal areas

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7
Q

What is the total dissolved load entering the ocean from rivers?

A

3.7 x 10^15g yr^-1

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8
Q

What is the total particulate load entering oceans from rivers?

A

15.5 x 10^15 g^yr-1

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9
Q

What are the origins of fluvial inputs?

A

Natural or anthropogenic(and pollutant)

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10
Q

What are the types of elements that can enter the oceans from the atmosphere?

A

Dry (particles) or wet (rainfall) disposition

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11
Q

What is an example of natural origin of elements from the atmosphere?

A

Windblown from mountains

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12
Q

What is an example of anthropogenic origin of elements from the atmosphere?

A

From power station chimney

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13
Q

What is try of elements entering oceans from the atmosphere?

A

• They may be in particulate or dissolved form — i.e. particles may subsequently dissolve
• Inputs will vary regionally

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14
Q

What is hydrothermal flux?

A

Hydrothermal flux is related to the mass flux of seawater by the water temperature anomaly and by the specific heat of seawater

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15
Q

What is true of hydrothermal fluxes to the ocean?

A

• Scale of inputs not well known for some may exceed riverine inputs — e.g. Li, Fe and Mn
• Some elements may precipitate very quickly on entering the seawater — e.g. iron and manganese oxides/black smoker chimneys

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16
Q

What is needed to understand the dissolved trace elements in the sea?

A

• Name & nature of chemical
• Its typical form in seawater
• Concentration
• Source and behaviour
• Distribution in the oceans

17
Q

How does lithium and caesium behave in seawater?

A

• Like sodium — and other alkali metals
• Little reactivity — conservative in seawater like sodium

18
Q

What is the source of caesium?

A

Reprocessing of nuclear wastes