Touch up #2 Flashcards
What is hydrocracking
upgrading of heavy oils by breaking long-chain molecules into smaller molecules using Hydrogen to saturated double bonds
Increases yield of transport fuels from heavy feedstocks, can crack more difficult components than catalytic cracker
What is hydrotreating
Similar methodolgy as hydrocracking, but targeting the removal of N and S
Capable of removing other components as well such as oxygen, halides and trace metals
H2 + catalyst reacts with oil to produce H2S and NH3 and saturated hydrocarbons
3 Methods to increase available heat
Oxyfuel rather than air
Operate close to the stoichiometric ratio, i.e avoid excess oxygen or fuel
Capture heat from flue gas by process-process heat exchange
Operational considerations of SMR
Temperature limit of reformer tubes (creep)
Carbon turning to coke: Autocatalytic, clogs reactor
Steam to carbon ratio 3-5
Autothermal
Singular reactor
Partial oxidation of hydrocarbons with SMR reaction
O2 required, cost and processing to generate
Two columns for methanol distillation
Topping: tops = dissolved volatile gases
Refining: MeOH comes out tops, by-products (higher alcohols), essentially pure water in bottoms
Products from atmospheric topper
Gas to LPG recovery Water LSR gasoline to treating Naptha Gas oil Topped crude oil
Products from vacuum distillation
Non-condensable gases Oily water Light VAC oil Heavy VAC oil Asphalt