topic C1-Atomic Structure and the Periodic Table Flashcards

1
Q

What is an atom?

A

An atom is the smallest part of an element

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2
Q

What is an element?

A

made up of only one type of atom

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3
Q

Elements may combine through chemical reactions to form new products; what are these new substances called?

A

compounds

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4
Q

What is a compound?

A

contains 2 or more different elements chemically combined in a fixed proportion

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5
Q

compounds can be separated by

A

chemical separation

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6
Q

What is a mixture?

A

A mixture consists of two or more elements or compounds not chemically combined together

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7
Q

mixtures are separated by

A

physical separations

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8
Q

What are the methods through
which mixtures can be separated
(there are five)? Do these involve

chemical reactions?

A
Filtration, 
crystallisation, 
simple distillation, 
fractional distillation
chromatography
 they do not involve chemical reactions
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9
Q

Describe and explain filtration

A

separates insoluble solids from liquids

  • filter paper placed in a funnel over a conical flask
  • pour mixture through the funnel
  • insoluble particles are left on the filter paper
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10
Q

Describe and explain crystallisation/evaporation.

A

used to separate a soluble solid from solvent by evaporation

-pour the solution into a evaporating dish
-gently heat the solution until all the solvent evaporates
-the solution
(crystallisation)
Crystallisation is similar, but we only remove some of the solvent by evaporation to
form a saturated solution Then,
we cool down the solution. As we do it, the solid starts to crystallise,

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11
Q

Required Practical 1 method-Making Salts

A
  • using a measuring cylinder measure (20 cm of sulfuric acid ) of acid into a beaker
  • add powdered metal into the acid and stir with a glass rod
  • continue adding the powder until it is in excess so no more reacting occurs eg fizzing
  • set up Filter using filter paper and funnel the solution to remove the excess solid (copper oxide.)
  • Pour the solution into the evaporating dish.
  • Evaporate the solution using a water bath until crystals start to form.
  • Leave the evaporating basin in a cool place for at least 24 hours.
  • Gently pat the crystals dry between two pieces of filter paper.
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12
Q

why do you need to put excess powder

A

so that no more reaction occurs

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13
Q

Describe and explain the simple distillation

A

Simple distillation is used to separate liquid from a solution – the liquid boils off and condenses in the condenser. The thermometer will read the
boiling point of the pure liquid.

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14
Q

the problem with simple distillation

A

if the solution of liquid have the same boiling point than the liquids cannot separate

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15
Q

explain

fractional distillation

A

Fractional distillation is a technique for separation of a mixture of liquids.

It works when liquids have different boiling points.

liquid with the lowest boiling point evaporates first

liquid with the highest boiling point condense at the bottom

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16
Q

simple distillation - method

A
  • start off by heating the solution eg using a Bunsen burner
  • the part of the solution with the lowest boiling point evaporates first
  • the liquid turns into vapour and passes into the condenser
  • the vapour then cools and condenses turning back into a liquid
  • crystal solids are left behind in the flask and the liquid is collected in the beaker
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17
Q

fractional distillation - method

A

The apparatus is similar to the one of simple distillation apparatus, with the
additional fractionating column placed on top of the heated flask.

The fractionating column contains glass beads. It helps to separate the compounds. The column is hot at
the bottom and cold at the top. The liquids will condense at different heights of the column.

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18
Q

Describe and explain chromatography

A

Chromatography is used to separate a mixture of substances dissolved in a solvent.

paper chromatography, we place a piece of paper with a spot containing a mixture
in a beaker with some solvent. The bottom of the paper has to be in contact with
the solvent. The solvent level will slowly start to rise, thus separating the spot (mixture) into few spots (components).

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19
Q

john Dalton

A

thoughts that atoms are tiny solid spheres that cannot be divided

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20
Q

jj Thomson

A

discovered electrons which led him to the plum pudding model

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21
Q

Describe the plum-pudding model

A

The atom is a ball of positive charge with negative electron embedded in it.

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22
Q

Ernest Ruthford

A

the alpha scattering particles experiment
which led him to the conclusion that mass of an atom was concentrated at the centre (nucleus) and that the nucleus is a positively charged

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23
Q

alpha scattering particle

A
  • a beam of alpha particles was fired at a thin gold foil
  • most particles went straight through the gold foil
  • some alpha particle was deflected and some repelled
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24
Q

what did the alpha scattering experiment tell us

A

most alpha particles went straight through therefore atoms are mainly empty space

some of the particles were deflected therefore the centre of an atom must have a positive charge

  • empty space
  • positive nucleus
  • surrounded by electrons
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25
Q

Neil Bohr

A

suggested the nuclear model

- suggested that electrons orbit the nucleus at a certain distance

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26
Q

Describe the Bohr/nuclear model and how it came about

A

The nuclear model suggests that electrons orbit the nucleus at specific
distances (shells) – it came about from the alpha scattering experiments

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27
Q

later on the experiment

A

led to the discovery of protons - positive particle in the nucleus

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28
Q

James Chadwick

A

included that the nucleus contains neutrons

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29
Q

overview of the plum pudding model

A
  • mainly empty space
  • positive nucleus
  • surrounded by negative electrons
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30
Q

overview of the nuclear model

A

electrons - orbit the nucleus at a specific distance - called shells or energy levels

the positive charge in the nuclear is due to tiny positive particles called protons

nucleus contains neutral particles called neutrons

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31
Q

State the relative charges

of the proton, neutron and electron

A

proton - +1
neutron- 0
electron - -1

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32
Q

State the relative mass

of the proton, neutron and electron

A

proton - 1
neutron - 1
electron -very small

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33
Q

What is the radius of an atom?

A

0.1 nm

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34
Q

What is the radius of a nucleus and
what is it compared to that of the

atom?

A

1 x 10-14 m and 1/10000

35
Q

What name is given to the number of protons in

the nucleus?

A

Atomic number

36
Q

Where is the majority of mass of an atom?

A

The nucleus

37
Q

What is the mass number?

A

The total number of protons and neutrons

38
Q

How does one calculate the
number of neutrons using mass
number and atomic number?

A

Subtract the atomic number from the mass number

39
Q

What is an isotope? Do isotopes of a certain element have the same chemical properties?

A

Atoms of the same element (same proton number) that have a different number of neutrons. They have the same chemical properties as they have the same
electronic structure

40
Q

What is the relative atomic mass?

A

The average mass value which takes the mass and abundance of isotopes
of an element into account, on a scale where the mass of 12C is 12.

41
Q

What are ions?

A

Ions are charged particles. They are formed when atoms lose electrons

(positive ions) or gain (negative ions) electrons.

42
Q

properties of metals

A
Boiling/meting point -High
Conductivity- good conductor of heat and electricity 
Appearance -Shiny
Malleability - yes 
Density - High
Oxides-Basic
43
Q

properties of non-metals

A
Boiling/meting point-low
Conductivity-cannot conduct
Appearance-dull
Malleability-brittle
Density-low
Oxides-acidic
44
Q

What is formed when a metal reacts with a

non-metal?

A

An ionic compound (made of positive and negative ions).

45
Q

What is formed when a non-metal reacts with a non-metal?

A

A molecular compound containing covalently bonded atoms.

Atoms share electrons, as opposed to transferring electrons between each other

46
Q

the periodic table

A

the elements are arranged in order of increasing atomic number

47
Q

The columns of the periodic table are called?

A

Groups

48
Q

group number

A

number of electrons in the outer shell

49
Q

The rows of the periodic table are called…?

A

Periods

50
Q

periods

A

number of shells

51
Q

Are elements in the same group similar or

different?

A

They may have similar chemical properties, as they have the same

number of outer shell electrons.

52
Q

Early periodic tables

A

john Newlands
-arranged the elements in order of atomic mass
-every 8th elements reacts in the same way
-the period was
incomplete and elements were
placed in inappropriate

53
Q

law of octaves

A

every 8th element reacts the same way and have similar properties

54
Q

Early periodic tables were incomplete and

elements were placed in inappropriate groups if what was to be followed?

A

The strict order of atomic mass

55
Q

Knowledge of what made it possible to explain
why the order based on atomic weights was not

always correct?

A

Isotopes

56
Q

modern periodic table

A

Dmitri Mendeleev

  • put the elements mainly in order of atomic mass but did switch /changed the order based on properties/weights
  • and left gaps for elements that have not been discovered yet
57
Q

Mendeleev overcame some problems with the table by doing what? He also changed the order of some elements based on what?

A

Leaving gaps and changing the order based on atomic weights

58
Q

Elements that react to form positive ions are…?

A

Metals

59
Q

Elements that do not form positive ions are…?

A

Non-metals

60
Q

Elements in Group 1 are known as…?

A

The alkali metals

61
Q

State three characteristics of

the Alkali Metals

A

-All have one electron in their outer shell
-have low density
-are stored under oil (to prevent reactions with oxygen or water)
are soft (can be cut
with knife)
-very reactive

62
Q

How do Group 1 elements react with

non-metals? Why are these reactions similar for the different Group 1 elements?

A

They form ionic compounds which are soluble white solids which form
colourless solutions – they all have one electron in their outer shell.

63
Q

reactivity in group one

A

the reactivity of the element increases as you go down the group . this is because the attraction between the nucleus and electrons decease

64
Q

How do Group 1 elements react with water?

A

They release hydrogen and form hydroxides which dissolve to form
alkaline solutions; react vigorously with water fizzing and moving around
on the surface of the water.

65
Q

lithium reacts with water

A

reaction with water - fizzes steadily floats/moves around

66
Q

lithium reacts with chlorine

A

white power

67
Q

lithium reacts with oxygen

A

produces white solid

burns with red flames

68
Q

sodium reacts with water

A

fizzes furiously melts into a ball disappears quicker

69
Q

sodium reacts with chlorine

A

clouds of white burns with yellow flame

70
Q

sodium reacts with oxygen

A

strong orange flame white solid

71
Q

potassium reacts with water

A

ignite with sparks

lilac flame , disappears quickly

72
Q

potassium reacts with chlorine

A

even more vigorous

73
Q

potassium reacts with oxygen

A

lilac flames

74
Q

group 7 also known as

A

halogens

75
Q

State five characteristics of Group 7

A
  • 7 electrons in outer shell
  • Coloured vapours
  • Diatomic molecules
  • Form ionic salts with metals
  • Form molecular compounds with non-metals
76
Q

fluorine

A

yellow gas and very reactive

77
Q

chlorine

A

green gas and fairly reactive and poisonous

78
Q

bromine

A

red-brown gas dense and poisonous

79
Q

iodine

A

grey as solid

purple as vapour

80
Q

State three changes that occur in Group 7 as one moves down the group

A
  • Higher relative molecular mass
  • Higher melting and boiling point
  • Less reactive – less easily gain electrons
81
Q

A more reactive halogen displaces a less reactive one from an aqueous solution of its salt; explain the trend in reactivity of halogens in these reactions

A

Reactivity decreases down the group. As we go down the group, the atoms
get larger, so an incoming electron will be less tightly held by the attractive forces
from the nucleus. That’s why Cl2
displaces Br–
and I–

82
Q

Compare group 1 metals with transition metals

A

Group 1 metals and transition metals are heat and electricity conductors.
They are shiny when polished and form ionic compounds with non metals.

Transition metals have higher densities and higher melting points than Group
1 metals. They are less reactive and harder than Group 1 metals.

83
Q

State three common characteristics of transition metals

A
  • Ions with different charges
  • Coloured compounds
  • Catalytic properties
84
Q

Describe the properties of noble gases. Discuss

the trends in properties down the group.

A

Non-metals, gases, low boiling points, unreactive (full outer shell; they don’t easily accept or lose electrons). The boiling point increases down the group, as the atoms get heavier.