AQA Chemistry GCSE Topic 2 - Bonding, Structure and the Properties of Matter Flashcards
What is ionic bonding?
- Ionic bonding is the electrostatic attraction between positive and negative ions.
- formed from metals combined with non-metals
- ionic bonds transfer electrons from one atom to another to achieve a full outer shell
How are ionic compounds
held together?
-They are held together in a giant lattice.
-Held together by strong electrostatic forces of attraction between oppositely
charged ions
-It’s a regular structure that extends in all directions in a substance.
State properties of ionic substances - boiling and melting points
High melting and boiling point because strong electrostatic forces between oppositely charged ions require a great deal of heat energy to break
State properties of ionic substances - conductivity
Do not conduct electricity when solid this is because the ions are held together by strong electrostatic forces of attraction In a fixed position
State properties of ionic substances - conductivity when liquid
ions can conduct electricity when melted or dissolved in water because the ions are free to move
What is a covalent bond?
- atoms share a pair of electrons
- there is electrostatic attraction between nucleus of atoms and the shared pair of electrons
- occurs in non-metals and non-metals
types of covalent bonds
simple molecules
large molecules
giant covalent
properties of simple
molecular covalent substances-conductivity
do not conduct electricity because molecules do not have an overall electric charge so no free ions
properties of simple
molecular covalent substances-boiling and melting points
low melting and boiling points
properties of simple
molecular covalent substances-state
as the temperature increases the vibration of the molecules increases at a certain point the vibration is strong enough to break the intermolecular forces at this point turn into a gas
gases or liquid in room temperature this id due to the weak intermolecular forces
properties of simple
molecular covalent substances-forces
the forces of attraction between these molecules are weak
How do intermolecular forces change as the mass/size of the molecule increases?
They increase.
That causes melting/boiling points to increase as well (more energy needed to overcome these forces).
examples of simple covalent
small molecules e.g. HCl,
H2 O2 Cl2 NH3 CH4
example of very large molecules,
polymers.
-Atoms in the polymer molecules are linked to other atoms by strong covalent
bonds
- Intermolecular forces between polymer molecules are relatively strong and so
these substances are solids at room temperature
What are
thermosoftening polymers?
type of polymers; they melt/soften when
heated. There are no bonds between polymer chains. Strong intermolecular forces
ensure that the structure is solid at room temperature. These forces are overcome with heating - polymer melts.
What are giant covalent
substances? Give examples
- atoms covalently bonded together in a giant lattice.
- High melting/boiling points - strong covalent bonds.
- Mostly don’t conduct electricity (no delocalised electrons)
- Diamond, graphite, silicon dioxide.
What is metallic bonding?
Forces of attraction between delocalised electrons and nuclei of metal ions.
-occurs in metallic elements and alloys metals and metals
properties of simple
molecular metallic bonds-structure
- Metals consist of giant structures of atoms arranged in a regular pattern.
- The electrons in the outer shell of metal atoms are delocalised and so are free to move through the whole structure.
- The sharing of delocalised electrons gives rise to strong metallic bonds
- metallic bonds are strong electrostatic attraction between positive metal ions and delocalised electron.
properties of metallic bonds -boiling and melting points
high melting and boiling points because the electrostatic forces between the metal atom and delocalised sea of electron are very strong so need lots of energy to break
properties of metallic bonds - conductivity
good conductor of heat and electricity because the delocalised electrons can carry electrical currents through the whole structure
Describe the properties of metals
-High melting/boiling points (strong forces of attraction)
- Good conductors of heat and electricity (delocalised electrons)
- Malleable, soft (layers of atoms can slide over each other whilst maintaining
the attraction forces)
-Good conductors of electricity because the delocalised electrons in the metal
carry electrical charge through the metal
- Good conductors of thermal energy because energy is transferred by the
delocalised electrons
What are alloys?
mixtures of metal with other elements, usually metal
Why are they harder than pure
metals?
different sizes of atoms distort the layers, so they can’t slide over each other,
therefore alloys are harder than pure metals
Describe and explain the
properties of allotropes of carbon-diamond
-formed from the element carbon
-each carbon is joined to 4 other carbons covalently.
very hard (Strong bonds)
- very high melting point (strong bonds)
- does not conduct (no delocalised electrons)
Describe and explain the
properties of allotropes of carbon-graphite
-formed from the element carbon
-each carbon is covalently bonded to 3 other carbons, forming
layers of hexagonal rings which have no covalent bonds between the layers.
-The layers can slide over each other due to no covalent bonds between layers
-weak intermolecular forces. Meaning that graphite is soft and slippery.
-conduct thermal and electricity due to one delocalised electron per each carbon atom
Fullerenes
–Molecules of carbon atoms with hollow shapes
– They are based on hexagonal rings of carbon atoms, but they may also
contain rings with five or seven carbon atoms
– The first fullerene to be discovered was Buckminsterfullerene (C60),
which has a spherical shape
Nanotubes
Cylindrical fullerenes with very high length to diameter ratios
Their properties make them useful for nanotechnology, electronics
and materials
uses of fullerenes
- pharmaceutical delivery
- lubricants
- catalysts
Graphene
- a single layer of graphite
-graphene is very strong because atoms within its layers are very
tightly bonded
What are the limitations of
the simple model?
- there are no forces of attraction
- all particles are shown as solid
- molecules and ions are solid spheres – this is not true
What does the amount of energy
needed to change state from solid
to liquid or liquid to gas depend on?
-The strength of the forces between the particles of the substance.
-The nature of the particles involved depends on the type of bonding and
the structure of the substance.
-The stronger the forces between the particles
the higher the melting point and boiling point of the substance
State the uses of nanoparticles
-Medicine (drug delivery systems)
- Electronics
- Deodorants
- Sun creams (better skin coverage and more effective protection
against cell damage)