AQA Chemistry GCSE Topic 2 - Bonding, Structure and the Properties of Matter Flashcards

1
Q

What is ionic bonding?

A
  • Ionic bonding is the electrostatic attraction between positive and negative ions.
  • formed from metals combined with non-metals
  • ionic bonds transfer electrons from one atom to another to achieve a full outer shell
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2
Q

How are ionic compounds

held together?

A

-They are held together in a giant lattice.
-Held together by strong electrostatic forces of attraction between oppositely
charged ions
-It’s a regular structure that extends in all directions in a substance.

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3
Q

State properties of ionic substances - boiling and melting points

A

High melting and boiling point because strong electrostatic forces between oppositely charged ions require a great deal of heat energy to break

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4
Q

State properties of ionic substances - conductivity

A

Do not conduct electricity when solid this is because the ions are held together by strong electrostatic forces of attraction In a fixed position

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5
Q

State properties of ionic substances - conductivity when liquid

A

ions can conduct electricity when melted or dissolved in water because the ions are free to move

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6
Q

What is a covalent bond?

A
  • atoms share a pair of electrons
  • there is electrostatic attraction between nucleus of atoms and the shared pair of electrons
  • occurs in non-metals and non-metals
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7
Q

types of covalent bonds

A

simple molecules
large molecules
giant covalent

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8
Q

properties of simple

molecular covalent substances-conductivity

A

do not conduct electricity because molecules do not have an overall electric charge so no free ions

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9
Q

properties of simple

molecular covalent substances-boiling and melting points

A

low melting and boiling points

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10
Q

properties of simple

molecular covalent substances-state

A

as the temperature increases the vibration of the molecules increases at a certain point the vibration is strong enough to break the intermolecular forces at this point turn into a gas

gases or liquid in room temperature this id due to the weak intermolecular forces

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11
Q

properties of simple

molecular covalent substances-forces

A

the forces of attraction between these molecules are weak

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12
Q

How do intermolecular forces change as the mass/size of the molecule increases?

A

They increase.

That causes melting/boiling points to increase as well (more energy needed to overcome these forces).

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13
Q

examples of simple covalent

A

small molecules e.g. HCl,

H2 O2 Cl2 NH3 CH4

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14
Q

example of very large molecules,

A

polymers.
-Atoms in the polymer molecules are linked to other atoms by strong covalent
bonds
- Intermolecular forces between polymer molecules are relatively strong and so
these substances are solids at room temperature

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15
Q

What are

thermosoftening polymers?

A

type of polymers; they melt/soften when
heated. There are no bonds between polymer chains. Strong intermolecular forces
ensure that the structure is solid at room temperature. These forces are overcome with heating - polymer melts.

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16
Q

What are giant covalent

substances? Give examples

A
  • atoms covalently bonded together in a giant lattice.
  • High melting/boiling points - strong covalent bonds.
  • Mostly don’t conduct electricity (no delocalised electrons)
  • Diamond, graphite, silicon dioxide.
17
Q

What is metallic bonding?

A

Forces of attraction between delocalised electrons and nuclei of metal ions.
-occurs in metallic elements and alloys metals and metals

18
Q

properties of simple

molecular metallic bonds-structure

A
  • Metals consist of giant structures of atoms arranged in a regular pattern.
  • The electrons in the outer shell of metal atoms are delocalised and so are free to move through the whole structure.
  • The sharing of delocalised electrons gives rise to strong metallic bonds
  • metallic bonds are strong electrostatic attraction between positive metal ions and delocalised electron.
19
Q

properties of metallic bonds -boiling and melting points

A

high melting and boiling points because the electrostatic forces between the metal atom and delocalised sea of electron are very strong so need lots of energy to break

20
Q

properties of metallic bonds - conductivity

A

good conductor of heat and electricity because the delocalised electrons can carry electrical currents through the whole structure

21
Q

Describe the properties of metals

A

-High melting/boiling points (strong forces of attraction)
- Good conductors of heat and electricity (delocalised electrons)
- Malleable, soft (layers of atoms can slide over each other whilst maintaining
the attraction forces)
-Good conductors of electricity because the delocalised electrons in the metal
carry electrical charge through the metal
- Good conductors of thermal energy because energy is transferred by the
delocalised electrons

22
Q

What are alloys?

A

mixtures of metal with other elements, usually metal

23
Q

Why are they harder than pure

metals?

A

different sizes of atoms distort the layers, so they can’t slide over each other,
therefore alloys are harder than pure metals

24
Q

Describe and explain the

properties of allotropes of carbon-diamond

A

-formed from the element carbon
-each carbon is joined to 4 other carbons covalently.
very hard (Strong bonds)
- very high melting point (strong bonds)
- does not conduct (no delocalised electrons)

25
Q

Describe and explain the

properties of allotropes of carbon-graphite

A

-formed from the element carbon
-each carbon is covalently bonded to 3 other carbons, forming
layers of hexagonal rings which have no covalent bonds between the layers.
-The layers can slide over each other due to no covalent bonds between layers
-weak intermolecular forces. Meaning that graphite is soft and slippery.
-conduct thermal and electricity due to one delocalised electron per each carbon atom

26
Q

Fullerenes

A

–Molecules of carbon atoms with hollow shapes
– They are based on hexagonal rings of carbon atoms, but they may also
contain rings with five or seven carbon atoms
– The first fullerene to be discovered was Buckminsterfullerene (C60),
which has a spherical shape

27
Q

Nanotubes

A

Cylindrical fullerenes with very high length to diameter ratios
Their properties make them useful for nanotechnology, electronics
and materials

28
Q

uses of fullerenes

A
  • pharmaceutical delivery
  • lubricants
  • catalysts
29
Q

Graphene

A
  • a single layer of graphite
    -graphene is very strong because atoms within its layers are very
    tightly bonded
30
Q

What are the limitations of

the simple model?

A
  • there are no forces of attraction
  • all particles are shown as solid
  • molecules and ions are solid spheres – this is not true
31
Q

What does the amount of energy
needed to change state from solid
to liquid or liquid to gas depend on?

A

-The strength of the forces between the particles of the substance.
-The nature of the particles involved depends on the type of bonding and
the structure of the substance.
-The stronger the forces between the particles
the higher the melting point and boiling point of the substance

32
Q

State the uses of nanoparticles

A

-Medicine (drug delivery systems)
- Electronics
- Deodorants
- Sun creams (better skin coverage and more effective protection
against cell damage)