Topic 8: Energetics I Flashcards
Enthalpy change & bond energy
Thermal energy stored in a chemical reaction, shown by change in temp
Bond energy: (E taken in to break bonds) - (E released when bonds are formed)
Specific to each covalent bond
Endothermic reactions
Products have more energy than reactants
Enthalpy change is +ve
E.g. photosynthesis, thermal decomposition
Exothermic reactions
Products have less energy than reactants (E is given out to surroundings)
Enthalpy change is -ve
E.g: combustion, neutralisation
Neutralisation
∆H when one mole of water is formed (acid + base -> water + salt)
Combustion
∆H when one mole of substance reacts completely with oxygen
Measuring ∆H experimentally
See how much a reaction changes the temperature of another substance (usually water)
Q (J) = m(g) * c (Jg-1°C-1) * ∆T
Specific heat capacity (c)
Quantity of energy in Joules needed to change the temperature of 1g of substance by one degree °C
For water & aqueous substances it is 4.18 Jg-1°C-1