Topic 7 VSEPR Flashcards

1
Q

What is the aim of the topic on Valence Shell Electron Pair Repulsion Theory (VSEPR)?

A

To draw Lewis structures, understand VSEPR, and determine the shape of a molecule.

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2
Q

What is ionic bonding?

A

Electrostatic attraction between atoms.

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3
Q

What is covalent bonding?

A

Sharing of electrons.

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4
Q

What is metallic bonding?

A

Metal atoms bonded to several other atoms.

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5
Q

Define electronegativity.

A

Ability of an atom to attract a shared pair of electrons in its combined state.

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6
Q

Define electropositivity.

A

Ability of an atom to withdraw a shared pair of electrons in its combined state.

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7
Q

What does Lewis structure represent in covalent bonding?

A

A covalent bond where two atoms are held together by a pair of shared electrons.

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8
Q

How are double and triple bonds represented in Lewis structures?

A

Double bond: two lines. Triple bond: three lines.

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9
Q

What role does the shape of a molecule play?

A

It plays an important role in its reactivity.

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10
Q

What determines the shape of a molecule according to VSEPR?

A

Electron pairs repel each other and are distributed as far apart as possible.

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11
Q

What is an electron domain?

A

The region in which electrons are most likely to be found, including lone pairs and bonds.

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12
Q

What is the best arrangement of electron domains according to VSEPR?

A

The arrangement that minimizes the repulsions among them.

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13
Q

What is the general formula for molecules with no lone pairs on the central atom?

A

ABx, where x is an integer usually 2 to 6.

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14
Q

How does the presence of lone pairs affect molecular shape?

A

Lone pairs occupy more space and experience greater repulsion than bonding pairs.

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15
Q

What is the order of repulsion forces in VSEPR theory?

A

Lone pair-lone pair > lone pair-bonding pair > bonding pair-bonding pair.

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16
Q

What are the three steps to predicting the shape of a molecule?

A
  • Draw a Lewis structure
  • Count electron pairs around the central atom
  • Distribute atoms and lone pairs as far apart as possible.
17
Q

What is the shape of ammonia (NH3)?

A

Pyramidal.

18
Q

What is the shape of water (H2O)?

A

Bent or V-shaped.

19
Q

What is the significance of bond angles in VSEPR theory?

A

Bond angles are determined by the arrangement of electron domains around the central atom.

20
Q

What should be noted about charges in oxyanions?

A

Negative charges usually reside on the oxygen atoms.

21
Q

How do you treat double and triple bonds in VSEPR calculations?

A

Treat them as single bonds.

22
Q

What is hybridization of the central atom?

A

The mixing of atomic orbitals to form new hybrid orbitals for bonding.

23
Q

What are the hybridizations associated with sp, sp2, and sp3?

A
  • sp: linear
  • sp2: trigonal planar
  • sp3: tetrahedral.