Topic 7 - rates of reaction and energy changes / SC18+19 Flashcards

1
Q

what is meant by Rate of reaction

A

the speed at which reactants are turned to porducts

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2
Q

what are ways to determine the rate in a reaction ( practical)

A

measuring the amount of gas produced
how fast the colour of the liquid changes

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3
Q

How do reactions occur in regards to particles

A
  • particles collide with each other
    the collisions must have enough activation energy
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4
Q

what is activation energy

A

the minimum energy needed by reactant particles for a reaction to happen

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5
Q

what does more energy result in

A
  • more successful collisions
  • faster reaction
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6
Q

how does temperature effect the rate of reaction

A
  • rate of reaction increases as temperature increases
  • the particles gains energy
  • particles move faster
  • the frequency of collisions increases so higher proportion of successful collision
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7
Q

how does concentration effect the rate of reaction

A
  • increased concentration, increases the rate of reaction
  • there are more particles in the same volume
    the frequency of successful collisions increases
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8
Q

how does surface are to volume ratio effect the rate of reaction

A

eg when lumps are made into powder
- increased surface area increased rate of reaction
- more particles of reactants available to react.
the frequency of successful collisions increases

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9
Q

what is a catalyst and what does it do

A
  • often transition metals
  • substances that speed up the rate of reaction.
  • they remain unchanged chemically or unchanged by mass
  • they provide alternative reaction pathways with a lower activation energy
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10
Q

how does a catalyst increase the rate of reaction

A
  • they provide alternative reaction pathways with a lower activation energy
  • so less energy is needed per collision for a reaction to occur
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11
Q

exothermic or endothermic?
neutralisation reaction
displacement reactions
precipitation reaction

A

neutralisation - always exothermic
displacement - always exothermic
precipitation - can be exothermic or endothermic

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12
Q

what is meant by exothermic

A

energy is transferred from stores of energy in a chemical reaction to the surroundings

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13
Q

what is meant by endothermic

A

energy is transferred from surroundings to stores of energy in a reaction

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14
Q

what does exothermic and endothermic reactions do to bonds

A

endothermic reaction break bonds
exothermic reaction make bonds

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15
Q

describe the overall heat change in an exothermic reaction

A

the reaction is exothermic if there is more heat released when forming the bonds in the product than is required in breaking bonds in the reactant
- the overall energy change decreases
- due to heat being taken from the surroundings to the reaction

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16
Q

describe the overall heat energy change for an endothermic reaction

A

the reaction is endothermic when
less heat energy is released un forming bonds in the product than is required in breaking bonds in the reactants
- overall energy change increase
- due to gaining energy from surrounding

17
Q

Calculate the energy change in a reaction given the energies of bonds (in kJ mol–1)

A

Step 1:
calculate the energy in bonds broken
Step 2:
calculate the energy out ( bonds broken)
Step 3:
energy change = energy in - energy out

18
Q

what is activation energy

A

the minimum amount of energy needed by colliding particles or a reaction to happen

19
Q

describe the reaction profiles for an exothermic reaction

A

-high heat energy for reactant
- small activation energy needed
- low heat energy from products
-large decrease in overall energy change

20
Q

describe the reaction profiles for an endothermic reaction

A
  • low heat energy for reactants
  • large activation energy needed
  • high heat energy of products
  • large increase in overall energy change