Topic 7: Gels and Emulsion Flashcards
Why is oil immiscible with water?
The attractive force between molecules of the same liquid is greater than the attractive forces between the two different liquids (if similar then they tend to be soluble)
Fats and oils are nonpolar
water is polar
what are “fat-in-water” examples of emulsions?
hollandaise (egg yolk w/ butter), mayonnaise (oil, egg yolks, vinegar/lemon juice), milk or cream
*fat dispersed in water
What are examples of “water-in-fat” emulsions?
vinaigrette (vinegar and oil), butter, margarine
*water dispersed in fat
what are the steps to making an emulsion?
- two phases, continuous phase (container of emulsion) and dispersed phase(the other liquid dispersed within)
- Emulsifier - liaisons between the two liquids to stabilize it (eg. amino acids, lecithin in egg yolks)
- mechanical force, shaking, stirring or blending, energy is used to bbreak up the dispersed phase and distribte it throughout the continuous phase evenly
- Stabilizer (or Thickner) to create more stable emulsion, makes the dispersed droplets more difficult to move. also thickens the emulsian
What are some examples of stabilizers (or thickeners)
porteins, starch, pectin, plant particles, and corn starch
what makes milk an emulsion?
- fat globbules are mixed into an oil-in-water emulsion
- casein proteins are in colloidal suuspension
- fat globules (larger) and casein micelles (smaller but large enough to deflect light) contribute to the opaque white color.
what is the outer surface of casein micelle made of
negatively charged kappa casein, these charges repel one another and thus are kept in solution
what does the addition of acids do to the kappa-casein molecules
the acids protonate kappa-casein molecules which causes them to lose their negataive chage, then binding together and becoming visible clumps in the milk
how does blending/whipping cream result in whipped cream?
the addition of tiny air bubbles when blending or whipping cream. the whipping action strips away the protective outer membrane of the fat globules, allowing the fat to join together, forming bubbles around tiny pockets of air. The fat holds air suspended in liquid stable
what happens when you keep whipping the cream?
the fat globules break open and release the fat molecules. The hydrophobic fat molecules clump together and mix to form larger solid fat and pushes out the liquid. This results in the creation of butter and buttermilk
What packing material is ideal for milk?
glass, it preserves milk flavor. plastic can also work, as it can also help maintain freshness in absence of light exposure
what kind of emulsion is ice cream?
fat in water emulsion, also foam
What state of matter is ice cream?
ice cream contains all three states, ice crystals (solid) fat globules, air bubbles (gas) dispersed in water/sugar (liquid)
Marketing grade of ice cream
Regular : ~10% milk fat
Premium : 12~14% milk fat
Super-premiu: >14% milk fat (denser, smoother, richer)
what is MNSF?
Milk solids non-fat which are proteins and mineral salts