Topic 6 - The rate and extent of chemical changes Flashcards

1
Q

rate of reaction =

A

rate of reaction = amount of reactant used (product formed) / time

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2
Q

What 2 units can be given to the rate of reaction?

A

g/s
cm^3/s

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3
Q

Name the 5 factors that affect the rate of reaction

A
  1. pressure of reacting gases
  2. concentration of reactants
  3. surface area of solid reactants
  4. temperature
  5. presence of catalysts
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4
Q

How does increasing the pressure of reacting gases affect the rate of reaction?

A

increasing the pressure means that the same number of particles will now occupy a smaller volume which leads to more frequent successful collisions between reacting particles and an increase in the rate of reaction.

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5
Q

How does increasing the concentration of reactants in a solution affect the rate of reaction?

A

Increasing the concentration increases the rate of reaction because there are a greater number of particles in the same volume to react which means that more frequent successful collisions between particles will occur.

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6
Q

How does increasing the temperature affect the rate of reaction?

A

increasing the temperature increases the kinetic energy of particles and increases the energy of each collision resulting in more frequent successful collisions between reacting particles. this means the rate of reaction increases

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7
Q

How does increasing the surface area of reactants affect the rate of reaction?

A

increasing the surface area of solid reactants increases the number of particles exposed and available to react which increases the frequency of collisions and rate of reaction

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8
Q

How does the presence of catalysts affect the rate of reaction?

A

They increase the rate of reaction by providing an alternate reaction pathway with lower activation energy. they do this without being used up.

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9
Q

What elements are most catalysts?

A

transition metals or there compounds

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10
Q

True or false:
Catalysts can be reused

A

true

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11
Q

Why do catalysts eventually need to be replaced?

A

they can become poisoned by impurities in the reaction

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12
Q

What type of catalysts are enzymes?

A

biological
(They work in biological systems)

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13
Q

What is ‘collision theory’ ?

A

chemical reactions can occur only when particles collide with eachother with sufficient energy and at the right orientation. The more frequent collisions, the higher the rate of reaction

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14
Q

What is activation energy?

A

the minimum amount of energy required for particles to react.

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15
Q

what is a reversible reaction?

A

the products of the reaction can react to produce the original reactants

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16
Q

The direction of the reaction can be changed by changing the __________

A

conditions (e.g forward hot backward cool)

17
Q

True or false:
reversible reactions never reach equilibrium

A

FALSE
REVERSIBLE REACTIONS WILL REACH EQUILIBRIUM

18
Q

What is dynamic equilibrium?

A

Dynamic equilibrium is when the rate of the forward reaction is equal to the rate of the reverse reaction in a closed sytem and the concentration of the reactants and products remain constant.

19
Q

What is an example of a reversible reaction?

A

Hydrated copper sulfate (blue) —– anhydrous copper sulfate (white) + water

20
Q

In this reversible reaction:
Hydrated copper sulfate (blue) —– anhydrous copper sulfate (white) + water
The forward reaction is endothermic. Is the reverse reaction endothermic or exothermic?

A

exothermic

21
Q

What is Le Chatelier’s principle?

A

If a system is at equilibrium and a change is made to any of the conditions, then the system responds to counteract the change

22
Q

What is Le Chatelier’s principle?

A

If you change the conditions of a reversible reaction, the system will try to counteract the change.