Topic 6 revision questions Flashcards

1
Q

What are reagents and conditions are required to convert chloropropane to propene?

A

Concentrated potassium hydroxide
Ethanol as a solvent and heat

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2
Q

What is the reagent used to convert chloropropane to butane nitrile?
(contains a CN group)

A

KCN

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3
Q

Why is the reaction adds a CN group to a halogenoalkane used in industry?

A

Increases chain length

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4
Q

Why do alkenes have stereoisomers?

A

c=c double bond cannot rotate.

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5
Q

Features of stereoisomers.

A

Same molecular and structural formula.
Different arrangement of atoms

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6
Q

How do you identify an E isomer?

A

If atoms with highest molecular formula are on different sides of the molecule.

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7
Q

Difference between cis and trans isomers?

A

Cis - If the same group are on the same side of the molecule
trans - If the groups are on either side of the molecule

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8
Q

Why do larger hydrocarbons have higher boiling points?

A

Intermolecular forces are stronger.

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9
Q

What does cracking produce?

A

An alkene and an alkane

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10
Q

What is a use of alkenes?

A

Making plastics

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11
Q

What is thermal cracking and what are the conditions?

A

Use of high temperatures and pressures
750 degrees and 70 atm

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12
Q

What is catalytic cracking?

A

Lower temperature and pressure
Use zeolite catalyst

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13
Q

What is the process of reforming?

A

Converting unbranched hydrocarbons into branched hydrocarbons.
Branched hydrocarbons burn more efficiently in vehicle engines.

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14
Q

What can acid rain do?

A

Kill aquatic animals
Kill trees

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15
Q

What compounds cause acid rain?

A

Sulfur dioxide
Nitrogen oxides

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16
Q

What do catalytic converters do?

A

Convert harmful gases to water vapor and oxygen

17
Q

What are the first and second ceramic blocks made out of in a catalytic converter?

A

1st - Platinum and rubidium
2nd - Platinum and Palladium

18
Q

Benefit of the metals used in catalytic converters?

A

High melting points
Never rust

19
Q

What do the microducts do in ceramic blocks?

A

Increase surface area

20
Q

What happens to the proportion of branched alkanes and cyclic hydrocarbons?

A

They both increase

21
Q

Why are tertiary carbocations more common than primary?

A

They are more stable
Alkyl groups push electrons towards it

22
Q

What apparatus is needed for cracking in a lab?

A

Gas syringe
Ceramic fibre soaked in alkane
Aluminium oxide catalyst
Heat the middle of test tube