(Topic 6) Rate And Extent Of Chemical Change (CGP book) Flashcards

1
Q

What is rate of reaction?

A

How fast the reactants are changed into products

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2
Q

Examples of rates of reaction?

A

Slow - Rusting
Moderate - Magnesium and acid
Fast - Burning and explosions

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3
Q

How to find rate of reaction?

A

Amount of product formed or reactant used up over time

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4
Q

Rate of reaction graphs?

A

Steeper line - faster rate of reaction
Over time line plateaus as reactants are used up

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5
Q

What is collision theory?

A

Collision frequency - More collisions there are, the faster the reaction
Energy transferred - Particles have to collide with enough energy to have a successful collision

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6
Q

What does rate of reaction depend on?

A

Temperature
Concentration of solution / pressure of gas
Surface area
Catalyst

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7
Q

How to increase rate of reaction?

A

Increase temp
Increase concentration/ pressure
Decrease surface area in which particles are
Use a catalyst

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8
Q

What is used to measure rate of reaction?

A

Gas = cm*3
Solid = (g)
Seconds = (s)

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9
Q

How to calculate mean rate of reaction from a graph?

A

Change in y / change in x

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10
Q

What is required for equilibrium to occur in a reversible reaction?

A

A closed system - no reactants of products can escape and nothing else can get in

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11
Q

Steps of a reversible reaction?

A
  • reactants react, their concentrations fall so forward reaction slows down
  • as more and more products are made, their concentrations rise so backward reaction speeds up
  • eventually, both are at same speed so system is at equilibrium
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12
Q

What happens at equilibrium?

A

Both forward and backward reactions are happening, but there is no overall effect, meaning concentrations of reactants and products have reached a balance and won’t change

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13
Q

What happens if equilibrium is at right?

A

Concentration of products is greater than reactants

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14
Q

What happens if equilibrium is at left?

A

Concentration of reactants is greater than that of products

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15
Q

What does the position of equilibrium depend on?

A

Temperature
Pressure
Concentration of reactants and products

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16
Q

What is le chateliers principle?

A

The idea that if you change the conditions of a reversible reaction at equilibrium, the system will try to counteract that change
Can be used to predict effect of any changes you make to a reaction system

17
Q

What happens if you decrease temperature in a reaction?

A

Equilibrium will move to exothermic direction to produce more heat, this means you will have more products for exothermic reaction and fewer for endothermic

18
Q

What happens if you raise temperature in a reaction?

A

Equilibrium moves to endothermic direction to try and decrease it, this means you will get more products for endothermic reaction and fewer for exothermic

19
Q

What happens to equilibrium if you change the pressure in a reaction?

A

(Only works for gases)
Increase - equilibrium tries to reduce so moves in direction of fewer molecules of gas
Decrease - equilibrium tries to increase sp moves in direction of more gas molecules

20
Q

What happens to equilibrium in a reaction if you change concentration?

A
  • change concentration of reactants or products, system no longer at equilibrium
  • system responds to bring back equilibrium
    Increase reactants - system tries to decrease by making more products
    Decrease products - system tries to increase by reducing amount of reactants