Topic 6 - Organic Chemistry 1 Flashcards

1
Q

What is a general formula?

A

An algebraic formula that can describe any member of a family of compounds

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2
Q

What is an empirical formula?

A

The simplest whole number ratio of atoms of each element in a compound

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3
Q

What is a molecular formula?

A

The actual number of atoms of each element in a molecule

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4
Q

What is structural formula?

A

Shows the arrangement of atoms carbon by carbon with the attached hydrogens and functional groups

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5
Q

What is skeletal formula?

A

Shows the bonds of the carbon skeleton only, with any functional groups.

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6
Q

What is displayed formula?

A

Shows how all the atoms are arranged, and all the bonds between them

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7
Q

What is a homologous series?

A

A group of compounds that have the same functional group and general formula, and differ by CH2

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8
Q

What is an addition reaction?

A

Joining two or more molecules together to form a larger molecule

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9
Q

What is a polymerisation reaction?

A

Joining together lots of simple molecules to form a giant molecule

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10
Q

What is an elimination reaction?

A

When a small group of atoms breaks away from a larger molecule

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11
Q

What is a substitution reaction?

A

When a species is replaced by another

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12
Q

What is a hydrolysis reaction?

A

Splitting a molecule into two new molecules by adding H+ and OH- derived from water

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13
Q

What are mechanisms?

A

Diagrams that break reactions down into individual stages. (Some mechanisms use curly arrows to show how electrons pairs move around when bonds are made or broken.)

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14
Q

What is a nucleophile?

A

An electron pair donor (often a negatively charge ion or species that contains a line pair of electrons, they’re electron rich, so they’re attracted to places that are electron poor)

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15
Q

What is an electrophile?

A

An electron pair acceptor (they’re electron poor, so they’re attracted to places that are electron rich. They react with negative ions, atoms with lone pairs and the electron-rich area around a C=C bond)

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16
Q

What is a radical?

A

A species with an unpaired electron

17
Q

What are structural isomers?

A

Isomers where the atoms are connected in different ways (the molecular formulas are the same but the structural formulas are different)

18
Q

What are chain isomers?

A

The carbon skeletons are arranged differently

Similar chemical properties, different physical properties (e.g. boiling point)

19
Q

What are positional isomers?

A

The functional groups are attached to different carbon atoms.

Different physical and chemical properties.

20
Q

What are functional group isomers?

A

The same atoms can be arranged into different functional groups.

Different physical and chemical properties.

21
Q

What happens in heterolytic fission?

A

The bond breaks unevenly with one of the bonded atoms receiving both electrons from the bonded pair

22
Q

What happens in homolytic fission?

A

The bond breaks evenly and each bonding atom receives one electron from the bonded pair. Two electrically uncharged radicals are formed

23
Q

What is a photochemical reaction?

A

A reaction started by light, e.g. UV light

24
Q

What happens in initiation?

A

Radicals are produced (UV light is required)

25
Q

What happens during propagation?

A

Radicals are used up and created in a chain reaction.

26
Q

What are the equations for the propagation reactions of Cl2 and CH4?

A

*Cl + CH4 —) *CH3 + HCl
*CH3 + Cl2 —) CH3Cl + *Cl

27
Q

What happens in termination?

A

Radicals react together

28
Q

What is cracking?

A

Breaking long-chain alkanes into smaller hydrocarbons (which can include alkenes)

29
Q

What is thermal cracking?

A

Takes place at very high temperatures and very high pressures
Produces a lot of alkenes

30
Q

What is catalytic cracking?

A

Uses a zeolite catalyst, at a slight pressure and high temperature
Mostly produces aromatic hydrocarbons and motor fuels