Topic 2 - Bonding and Structure Flashcards

1
Q

What is an ionic bond?

A

The strong electrostatic attraction between two oppositely charged ions.

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2
Q

What are isoelectronic ions?

A

Ions of different atoms with the same number of electrons

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3
Q

Why do lattices form?

A

Each ion is electrostatically attracted in all directions to ions of the opposite charge

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4
Q

Explain how the migration of ions is evidence for the presence of charged particles.

A

When you electrolyse a green solution of copper (II) chromate (VI) on a piece of wet filter paper, the filter paper turns blue at the cathode (negative electrode) and yellow at the anode (positive electrode).
Copper (II) ions are blue in solution and chromate (VI) ions are yellow.
When you pass a current through the solution, the positive ions move to the cathode and the negative ions move to the anode.

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5
Q

What is a covalent bond?

A

The strong electrostatic attraction between two positive nuclei and the shared electrons

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6
Q

What is a dative covalent bond?

A

A covalent bond where one atom donates both electrons

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7
Q

What is the name of the structure and bond angle if it has 2 electron pairs around the central atom?

A

Linear
180°

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8
Q

What is the name of the structure and bond angle if it has 3 bonding pairs around the central atom?

A

Trigonal planar
120°

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9
Q

What is the name of the structure and bond angle if it has 2 bonding pairs and 1 lone pair around the central atom?

A

Non-linear
119°

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10
Q

What is the name of the structure and bond angle if it has 4 bonding pairs around the central atom?

A

Tetrahedral
109.5°

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11
Q

What is the name of the structure and bond angle if it has 3 bonding pairs and 1 lone pair around the central atom?

A

Trigonal pyramidal
107°

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12
Q

What is the name of the structure and bond angle if it has 2 bonding pairs and 2 lone pairs around the central atom?

A

Non-linear
104.5

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13
Q

What is the name of the structure and bond angle if it has 5 bonding pairs around the central atom?

A

Trigonal bipyramidal
120°
90°

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14
Q

What is the name of the structure and bond angle if it has 4 bonding pairs and 1 lone pair around the central atom?

A

Seesaw

. F
. F(b)|
.(a) > S xx
. F |
. F

a = 102°
b = 87°

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15
Q

What is the name of the structure and bond angle if it has 3 bonding pairs and 2 lone pairs around the central atom?

A

Distorted T

. F
.xx |
. Cl — F
.xx |
. F

87.5°

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16
Q

What is the name of the structure and bond angle if it has 6 bonding pairs around the central atom?

A

Octahedral

. F
.F | F
. >S<
.F | F
. F

90°

17
Q

What is the name of the structure and bond angle if it has 5 bonding pairs and 1 lone pair around the central atom?

A

Square pyramidal

. F (b)
. F | F
. >I< (a)
. F F

a = 90°
b = 81.9°

18
Q

What is the name of the structure and bond angle if it has 4 bonding pairs and 2 line pairs around the central atom?

A

Square planar

F xx F
>Xe<
F xx F

90°

19
Q

What does electronegativity mean?

A

The ability of an atom to attract the bonding electrons in a covalent bond

20
Q

What is a dipole?

A

A difference in charge between two atoms caused by a shift in electron density in the bond.