Topic 5 Test Review Flashcards

1
Q

standard states

A

298K
1.00 x10⁵ Pa

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2
Q

standard enthalpy change of formation (ΔHf)

A

the enthalpy change that results when one mole of a compound is formed from its elements (in their standard states)

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3
Q

temperature

A

average kinetic energy of molecules

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4
Q

heat

A

amount of energy exchanged due to temperature difference between two substances (higher temp.<–> lower temp.)

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5
Q

enthalpy change

A

The change in internal (chemical) energy (H) in a reaction
(the enthalpy itself cannot be measured so we measure the change instead)
ΔH exothermic = (-)
ΔH endothermic = (+)
STABILITY
exothermic < endothermic

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5
Q

exothermic

A

((-)ΔH) heat energy transferred from system to surroundings ⁻⁻|_

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6
Q

endothermic

A

((+)ΔH) system takes energy from surroundings _|⁻⁻

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7
Q

common experimental errors

A
  • heat loss to the environment
  • incoplete combustion
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8
Q

surrounding vs system

A

the surrounding is everything the system is NOT

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9
Q

ΔHBE ; ΔHc ; ΔHf

A

bond enthalpy/energy; combustion enthalpy; formation enthalpy

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10
Q

specific heat capacity and density of water

A

4.18 Jg⁻¹k⁻¹ ; 1.00 g/cm³

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11
Q

bond energy

A

amount of energy required to break a bond. (endothermic (+)) (kJ/mol)

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12
Q

calculating ΔHrxn in terms of ΔHf

A

(ΔHf of products) - (ΔHf of reactants)

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13
Q

calculating ΔHrxn in terms of ΔHBE

A

(ΔHBE of reactants) - (ΔHBE of products)

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14
Q

ºC —> K

A

+ 273

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15
Q

n = CV

A

moles = concentration * volume

16
Q

calculating ΔHrxn in terms of ΔHc

A

(ΔHc of reactants) - (ΔHc of products)

17
Q

Percentage Difference Formula

A

(Exp - Lit)/Lit *100