Topic 5: Energetics Flashcards

1
Q

Exothermic reaction

A

heat is given away to the rest of the universe creating more thermodynamicly stable products than reactants.

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2
Q

Energy

A

Ability to do work (heat)

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3
Q

System

A

the area of interest, the place where the chemical reaction occurs.

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4
Q

Open system

A

can exchange matter and energy with the rest of the universe

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5
Q

Closed system

A

can exchange energy with the rest of the universe but not matter.

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6
Q

Enthalpy

A

“the heat inside” - the reservoir of energy in a compound

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7
Q

Endothermic

A

heat is used by the system and have to be added from the suroundings

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8
Q

Common exothermic reaction; Combustion reactions

A

When a compound is bured in excessor oxygen CO2 and water as products

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9
Q

Common exothermic reaction; Neutralization reactions

A

e.g. when HCL reacts with NaOH or be precise. Energy Always negative

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10
Q

Common endothermic reaction; Photosynthesis

A

6CO2 (g) + 6H2O -> C6H12C6 (aq) + 6O2 (g)

Energy always positive, because it is needed for the reaction to take place.

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11
Q

What does the increase in temperature depend on?

A
  • the mass of the object
  • the heat added
  • the nature of the substance
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12
Q

What is the formula for heat change.

A

Heat change = mass x specific heat capacity x temperature change

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13
Q

When does endothermic reactions occurs?

A

When there is an increase in disorder of the system.

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14
Q

What is enthalpy change of combustion?

A

The heat produced when one mole of a substance is burned in excess oxygen

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15
Q

The standard enthalpy of formation of a substance?

A

The enthalpy change that occurs when one mole of the substance is formed from its elements in their standard states under standard conditions

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16
Q

What does Hess’s law state?

A

The enthalpy change for any chemical reaction is independent of the route, provided the start conditions and final conditions, and reactants and products, are the same.

17
Q

The bond enthalpy?

A

The energy needed to break one mole of bonds in gaseous molecules under standard conditions.

18
Q

Endothermic in bond enthalpy?

A

Separation of particles which are held together by a force of attraction.

19
Q

Exothermic in bond enthalpy?

A

The bringing together of particles which have an attractive force between them.