Topic 3 - reactions of metals with water & acids Flashcards
Reactions with water - Group 1 (alkali metals):
React violently with water
Reactivity increases down the group
Produce a basic solution
2M(s) + 2H2O(l) → 2M+(aq) + 2OH-(aq) + H2(g)
Reactions with water - Group 2 (Alkali Earth metals)
Beryllium doesn’t react
Magnesium will react with steam
Metals below magnesium will react with water, reaction becomes more vigorous down the group
Reaction produces hydroxides – basic solutions
M(s) + 2H2O(l) → M(OH)2(aq) + H2(g)
Reactions with water - Group 3,4,5,6 + transition metals
Group 3: Aluminium appears not to react at all due to the surface oxide layer Other group 3 metals are not very reactive with water Group 4, 5, 6: No reaction Transition metals: Slow reaction if any
Reactivity series
List of metals from most to least reactive
Reactivity in metals depends on how easily the metal atom loses an electron to have full shells
The more reactive the metal, the harder it is to extract from it’s ore and the more likely it is found as a compound
Patterns of reactivity
Reactivity of metals decreases across periods because the higher the nuclear charge, the harder it is to lose an electron
The most reactive metals are in group 1
Reactivity increases down group 1 as the atoms get bigger
The order of reactivity is Group 1, Group 2, Group 3, Group 4, Transition metals
Why are there non-metals?
Carbon is included as some metals can be extracted from ore by displacement with carbon
Hydrogen is present as metals below hydrogen will not react with dilute acids or water
Reactions with dilute acids
Metals above copper can react to form metal salts and hydrogen
Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)
More reactive metals will also form salts but the reaction is very violent and therefore dangerous
Reactions of calcium, strontium and barium with sulphuric acid are more complex as they produce insoluble sulfates which form a protective layer