Topic 3 - Equations, Calculations & Electrolysis Flashcards
relative atomic mass (Ar)
average mass of all isotopes of that element
relative formula mass (Mr)
sum of relative atomic masses in a compound
how to find percentage mass of an element within a compound
Ar of element / Mr of compound
Moles equation
Moles = mass / Mr
Avogadro Number
6.02x10^23
conservation of mass
in a chemical reaction, no atoms are created or destroyed, the bonds are just changed
why might the mass of products be less than the reactants?
- reactants could have spilled
- products (if gas) could have floated off
why might the mass of products be greater than the reactants?
- gas from air reacting with reactants
Calculating mass in reactions
- write out balanced equation
- find moles of known substance (moles = mass/mr)
- find moles of unknown substance (using molar ratio)
- find mass of unknown substance (mass = moles x mr)
Volume of gas at RTP equations
Volume = moles x 24 dm^3
Volume = moles x 24,000 cm^3
cm -> dm = /1000
Concentration equation
concentration = mass / volume
molecular formula
actual number of atoms of each element in a compound or molecule
empirical formula
smallest whole number ratio of each element in a compound or molecule
Finding empirical formula
Create a table with all elements separated
- identify mass
- find moles (mass/mr)
- divide by smallest number of moles
- find ratio!
Finding molecular formula
- Divide unknown compound’s Mr by Mr of empirical formula
- multiply all numbers in formula by the result of division
Water of crystallisation
when salt crystals contain water molecules
hydrated -> contain water
anhydrous -> do not contain water
E.g. anhydrous copper sulfate turns blue when water is added
How is water of crystallisation shown?
Using a dot followed by the number of water molecules there are.
Percentage yield equation
yield obtained / theoretical yield
x100
why might the percentage yield be less than 100%
- reactants may not all react
- products may be lost to surroundings
electrolysis
when an electric current passes through a substance and causes it to break down
positive electrode
anode
where negative ions go
negative electrode
cathode
where positive ions go
Oxidation
gain of oxygen, loss of electrons
OILRIG
Reduction
loss of oxygen, gain of electrons
OILRIG