Topic 3 – Chemical Changes Flashcards
Explain the meaning of weak acid
• partially ionised
• concentration of H+ ions lower
Define electrolytes
Ionic compound in molten state/dissolved in water
Define electrolysis
A process in which electrical energy/ electricity (from a direct current supply) decomposes electrolytes
Cations (positively charged ions) move towards the…
Cathode (negative electrode)
• REDUCED (gains electrons) so mass increases
Anions (negatively charged ions) move towards the…
Anode (positive electrode)
• OXIDISED (loses electrons) so mass decreases
What ions are present at the cathode?
H+ and metal ions
When is hydrogen produced at the cathode?
Hydrogen produced if metal is more reactive than hydrogen (e.g. sodium)
When are metals produced at the cathode?
Metal produced if it’s less reactive than hydrogen (e.g. copper, silver)
What happens when OH- & halide ions are present at the anode?
• if ionic compound contains halide ions, the halogen is produced (Cl2)
What happens when OH- & halide ions are NOT present at the anode?
• Oxygen produced if no halide ions are present (Cl, Br, I)
What are the products formed when a sample of molten potassium bromide is electrolysed?
Potassium & bromine
• Potassium (more reactive than Hydrogen)
• Bromine (halide ion)
Test for Hydrogen
• Lit splint
• Burns with a squeaky pop
State why it is important that the electrodes are inert
inert electrodes do not react with the electrolyte
Explain, in terms of structure, how graphite conducts electricity
• electrons
• move (through graphite)
• are delocalised/ free to move
Explain why mass decreases at anode
• Atoms become ions
• Atoms are oxidised (lose electrons)
• ions move into solution
Explain why mass increases at cathode
• Ions become atoms
• Ions are reduced (gain electrons)
• Ions move out of solution
Molten lead bromide can be electrolysed to form molten lead and bromine gas. Explain how a student can set up an apparatus to carry out this electrolysis (2)
• Use a crucible (instead of beaker)
—> so it doesn’t break (when heated strongly)
Explain what should be done to copper electrodes before their masses are determined
• Electrodes should be cleaned (using emery paper)
• to remove impurities
Explain how Hydrogen gas is formed at the cathode
• hydrogen ions attracted to cathode
• hydrogen ions are reduced (gain 2 electrons)
State what equipment could be used to measure the volume of a gas
• measuring cylinder
• burette
• gas syringe