topic 3 - bonding Flashcards

1
Q

Explain the formation of ions in ionic compounds from their atoms, in groups 1, 2, 6 and 7

A

Groups 1+2: lose electrons to form cations
Groups 6+7: gain electrons to form anions

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2
Q

When are the endings -ide and -ate used?

A

-ide: an anion that contains oxygen and at least one other element
-ate: an anion that contains only one element

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3
Q

How do you find the formula of an ionic compound by balancing charges?

A

The charges of ions need to be balanced.
To make a neutral compound one cation needs to combine with an anion - this pairing ensures the compound has an overall neutral charge

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4
Q

Explain the structure of an ionic compound

A
  • Lattice structure formed by strong attractions between oppositely charged ions
  • Due to the powerful electrostatic forces between the ions, the compound has a HMP/HBP
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5
Q

How is a covalent bond formed?

A

When a pair of electrons is shared between two atoms. This helps them reach a stable state and achieve a strong bond

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6
Q

What is the result of covalent bonding?

A

Molecules are formed, where atoms share electrons to form stable units

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7
Q

Recall the typical size (order of magnitude) of atoms and small molecules

A

Atom: typically about 0.1 to 0.5 nanometres
Small molecules: range from about 0.1 to a few nanometers in size

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8
Q

What do dot and cross diagrams represent?

A

the outer shell electrons of each atom using dots for one element and crosses for another element.

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9
Q

Hydrogen (H2) - Dot and cross

A
  • Sharing single electron
  • single covalent bond
  • diagram displays 2 hydrogen atoms sharing a pair of electrons
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10
Q

Hydrochloric acid (HCl) - Dot and cross

A
  • H + Cl share an electron to form a single covalent bond
  • hydrogen has 1 electron and chlorine has 7, indicating their sharing to complete their outer shells
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11
Q

Water (H2O) - dot and cross

A
  • O2 shares 2 electrons with 2 hydrogen atoms to form 2 covalent bond
  • diagram shows O2 sharing 2 pairs of electrons, 1 pair with each hydrogen atom.
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12
Q

Methane (CH4) - dot and cross

A
  • Carbon (C) forms 4 covalent bonds, each has 1 H atom by sharing its 4 outer electrons
  • diagram shows C sharing 1 electron with each of the 4 H atoms.
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13
Q

Oxygen (O2) - dot and cross diagrams

A
  • 2 O2 atoms share 2 pairs of electrons, forming a double covalent bond between them
  • diagram displays both oxygen atoms sharing two pairs of electrons.
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14
Q

Carbon Dioxide (CO2) - dot and cross

A
  • 1 C atom shares 2 pairs of electrons with 2 O atoms, forming 2 double covalent bonds
  • diagram shows C sharing 2 pairs of electrons with each O atom.
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15
Q

Why can elements and compounds be classified as ionic?

A

Result from electron transfer between atoms, forming charged ions that attract each other.

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16
Q

Why can elements and compounds be classified as simple molecular (covalent)?

A

Atoms share electrons, forming weakly bonded molecules with lower melting points and no conductivity.

17
Q

Why can elements and compounds be classified as giant covalent?

A

Feature strong covalent bonds in extensive networks, resulting in high melting points. Some, like graphite, can conduct electricity.

18
Q

Why can elements and compounds be classified as metallic?

A

Comprised of metal atoms sharing a “sea” of electrons, leading to good conductivity and other typical metallic properties.

19
Q

Explain how the structure and bonding of substances results in different physical properties

A
20
Q

Why do ionic compounds have high melting/boiling points?

A

Due to strong electrostatic forces of attraction between oppositely charged ions, within the lattice structure. A lot of energy is needed to break this attraction.

21
Q

Why do ionic compounds conduct electricity?

A

When molten and dissolved the ions become free to move and carry the electric charge. (Not in solids as the ions are fixed)

22
Q

Properties of typical covalent, simple molecular substances:

A
  • LMP/LBP
  • Don’t conduct electricity
  • Some are soluble in water, some aren’t
23
Q

Why do typical covalent, simple molecular compounds have low melting/ boiling points?

A

Mostly gases or liquids at room temp, as the molecules get smaller, less energy is needed to break the weaker forces between them

24
Q

Why do typical covalent, simple molecular compounds not conduct electricity?

A

There are no charged particles to carry charge

25
Q

What are giant covalent structures?

A

Solids containing atoms which are all bonded to each other by strong covalent bonds

26
Q

3 properties of giant covalent structures:

A
  1. HMP/HBP - Lots of energy needed to overcome strong covalent bonds
  2. Don’t conduct electricity (except for a couple exceptions) - no charged particles to carry charge
  3. Not soluble in water
27
Q

What are graphite and diamond?

A
  • examples of giant covalent substances
  • both carbon allotropes (different forms of carbon)
28
Q

Diamond (bonding, properties, conductivity, uses)

A

Bonding: C atoms form 4 covalent bonds
Properties: Very hard
Conductivity: doesn’t conduct electricity
Uses: cutting tools (because of hardness)

29
Q

Graphite (bonding, properties, conductivity, uses)

A

Bonding: C atoms form 3 covalent bonds. No covalent bonds between layers
Properties: soft, slippery
Conductivity: conducts electricity and heat
Uses: electrodes (conductor), lubricant (lubricating)

30
Q

Describe structure of diamond:

A

C atoms form a rigid 3D lattice, each C atom bonds to 4 others in a 3D lattice, creating extreme hardness.

31
Q

Describe structure of graphite:

A

C atoms form layers with strong bonds within each layer but weak forces between them, allowing for lubrication and conductivity along the layers.

32
Q

What is a fullerene?

A

Have hollow shapes, giving them large surface areas

33
Q

Properties of C60 (structure and bonding)

A

Structure: spherical C molecules with rings of 6 C atoms (sometimes 5 or 7), in hexagons
Bonding: strong covalent bond between C atoms creating a closed cage structure

34
Q

Properties of graphene (structure and bonding)

A

Structure: Single layer of carbon atoms arranged in a 2D hexagonal lattice.
Bonding: C atoms form 3 strong covalent bonds between C atoms