Topic 1b: Moist Thermodynamics Flashcards
What is the composition of the atmosphere?
Nitrogen (78%)
Oxygen (21%)
Argon (1%)
Water vapour (0-5%)
What does Md stand for?
molecular weight of dry air. Md = 28.97
How do you find the mass of moist air?
Madd = Cd Md + Cv Mv
= Cd x 28.97 + Cv x18.02
note: Cd + Cv = 1
Moist air is ___ dense than dry air. why?
less. because the water vapour molecules replace heavier molecules.
what is Daltons law of partial pressures:
Total pressure exerted by a mixture of gases that dont react chemically is equal to the sum of the partial pressures of each gas.
What is the partial pressure law for moist air?
P = p’d + e
Where p’d is the partial pressure of dry air
e = the partial pressure of water vapour
What expression can be used to determine partial pressure of dry air?
p’d = rho’d Rd T
What expression can be used to determine partial pressure of water vapour/
e = rho’v Rv T
where Rv = 461. 5 JK^-1Kg^-1
What is the value of ‘3’?
0.622
Rd/Rv
What does this equation tell you:
density of moist air. an increase in e (water vapour) decreases the density
Define virtual temperature? formula?
Virtual temperature is the temperature that dry air would need to attain to have the same density as the moist air at the same temperature.
note virtual temperature is always greater than actual temperature
What are thee measures of water vapour content in air?
1.
2.
3.
- e = partial pressure in Pa or hPa
- mixing ratio = Mv/Md
- q = specific humidity = w / (1+w) given in g/kg
When there is no condensation or evaporation mixing ratio is…
conserved
Define vitual potential temperature
virtual theta is conserved in the absence of condensation. Equation is a better measure of stability in a moist atmosphere.
Define saturation
The point at which air holds as much water vapour as it can. this amount decreases when temperature decreases.