Topic 12 - Acid-base Equilibria Flashcards
Brønsted-Lowry acid
A proton donor
Brønsted-Lowry base
A proton acceptor
Conjugate acid/base pair
Two species left over as a result of a proton donation
pH
A figure expressing the acidity/alkalinity of a solution on a logarithmic scale
-log10([H+])
Ka
Acidic dissociation constant
pKa
-log10(Ka)
Lower the pKa, stronger the acid
Kw
Ionic product of water
10^-14
Lewis acid
Electron pair acceptor
Lewis base
Electron pair donor
Strong acid
Acid that dissociates completely in water
Strong base
Base that dissociates completely in water
Weak acid
Acid which dissociates slightly in water
Weak base
Base that dissociates slightly in water
Amphoteric
Substance that can act as an acid and a base
eg. HCO3 -
Monoprotic acid
Can release only one H+ ion upon dissociation
Polyprotic acid
Can release multiple H+ ions upon dissociation
Equivalence point
The point when full neutralisation occurs
Buffer
Solution that resists change in pH when small amounts of strong acid/base are added
large amount of strong acid/base + salt (i.e. conjugate base/acid)
Acidic buffer
A buffer containing a weak acid and its conjugate base
Alkaline buffer
A buffer containing a weak base and its conjugate acid