Topic 12- Acid Base Equilibria Flashcards
Define a Bronsted-Lowry acid
a proton donor
Define a Bronsted-Lowry base
A proton acceptor
Define a buffer solution
A solution made up of large amounts of weak acid and conjugate base to resist pH changes when small volumes of H+ and OH- are added.
In the reaction of propanoic acid and sodium propanoate, why is the equivalence point not at 7?
At equivalence point, propanoate ions are present
-the propanoate ions react with water molecules and form OH- ions
-hence increasing the pH
propanoate ions + water = OH- ions + propanoic acid
Define enthalpy change of neutralisation
the enthalpy change when an acid neutralises an alkali to form one mole of water under standard conditions
How does buffer action work in the blood?
Carbonic acid and hydrogencarbonate form an equlibrium reaction within the blood
-adding alkali shifts equilbrium to the right as water is formed
-adding acid shifts equilibrium to the left as carbonic acid is formed
Overall equation: H2CO3(aq) ⇌ H+(aq) + HCO3–(aq)