Thermodynamics Energy Basics Chapter 5.1 Flashcards

1
Q

Thermochemistry

A

area of science concerned with the amount of heat absorbed or released during chemical and physical changes

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2
Q

Energy

A

capacity to supply heat or do work

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3
Q

potential energy

A

the energy an object has because of its relative position, composition, or condition

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4
Q

Kinectic energy

A

the energy that an object possesses because of its motion

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5
Q

The law of conservation of energy:

A

during a chemical or physical change, energy can be neither created nor destroyed, although it can be changed in form

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6
Q

The law of conservation of matter

A

During any physical or chemical change, the total mass of the products remains equal to the total mass of the reactants.

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7
Q

Thermal energy

A

kinetic energy associated with the random motion of atoms and molecules

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8
Q

Temperature

A

Hotness or coldness of an object

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9
Q

When the atoms and molecules in an object are moving or
vibrating quickly, they have a …. and we say that the object is ___

A

higher average kinetic energy (KE),

hot

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10
Q

When the atoms and molecules are moving slowly, they have …, and we say that the object is “___”

A

lower average KE

cold

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11
Q

Assuming that no chemical reaction or phase change (such as melting or vaporizing) occurs, increasing/decreasing the amount of thermal energy in a sample of matter …..

A

will cause its temperature to increase. And, assuming that no chemical reaction or phase change (such as condensation or freezing) occurs, decreasing the amount of thermal energy in a sample of matter will cause its temperature to decrease.

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12
Q

Heat

A

The transfer of thermal energy between two bodies at different temperatures

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13
Q

What does Heat flow do

+when does it stop?

A

Increases the thermal energy of one body and decreases the thermal energy of the other. Heat flow will continue until the two substances are at the same temperature

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14
Q

Exothermic process

A

A chemical reaction that RELEASES heat (has a negative ΔH).

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15
Q

Endothermic process

A

A reaction or change that absorbs heat

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16
Q

Thermal equilibrium (3)

A

Both substances are at the
- same temp
- their molecules have same average kinectic energy.

No net flow of thermal energy between them when they are connected by a path permeable to heat.

17
Q

Calories+why its not used as a unit for energy (3)

A

The amount of energy required to raise one gram of water by 1 degree C (1 kelvin).

However, this quantity depends on the atmospheric pressure and the starting temperature of the water.

18
Q

The SI unit of heat, work, and energy

A

Joule

19
Q

Joule

A

the amount of energy used when a force of 1 newton moves an object 1 meter.

20
Q

heat capacity (C)

A

the quantity of heat (q) it absorbs or releases when it experiences a temperature change (ΔT) of 1 degree Celsius (or equivalently, 1 kelvin):

21
Q

heat capacity (C)
(3)

+formula+ trait+what it is

A

the quantity of heat (q) it absorbs or releases when it experiences a temperature change (ΔT) of 1 degree Celsius (or equivalently, 1 kelvin)

extensive property

22
Q

What is heat capacty determined by?

A

Heat capacity is determined by both the type and amount of substance that absorbs or releases heat.

23
Q

extensive property

A

its value is proportional to the amount of the substance.

24
Q

Why is heat capacity dependent on mass? (2)

Use pan as the compared example +what’s the relationship with mass and HC?

A

More mass means more atoms are present in the larger pan, so it takes more energy to make all of those atoms vibrate faster.

The larger pan has a (proportionally) larger heat capacity because the larger amount of material requires a (proportionally) larger amount of energy to yield the same temperature change

25
Q

heat capacity and mass relationship

A

They are directly porportional

26
Q

The specific heat capacity (c)

(4)

+formula+what it depends on+the property vocab

A
  • the quantity of heat required to raise the temperature of 1 gram of a substance by 1 degree Celsius (or 1 kelvin)
  • depends only on the kind of substance absorbing or releasing heat
  • intensive property
27
Q

Intensive property

A

a physical quantity whose value does not depend on the amount of substance which was measured.

ex: specific heat capacity. The mass doesnt change the SPH value

28
Q

Specific heat capacity is derived from

hint: 2 extensive properties

A

being derived from a ratio of two extensive properties (heat and mass).

Heat is an extensive property, and is proportional to the total energy of all atoms in an object.

29
Q

specific heat capacity/ heat capacity value of large and small pan example exaplanation:

*same diff?

A

Because of its larger mass, a large frying pan has a larger heat capacity than a small frying pan. Because they are made of the same material, both frying pans have the same specific heat.

30
Q

Enthalpy change is the heat change when

A

Enthalpy change equals Heat change at constant pressure.