Textbook Topic 9- Gas law Flashcards

1
Q

Gas pressure is caused by… although the force is small…..

A

the force exerted by the gas molecules colliding with the surfaces of objects. Although the force of each collision is very small a large SA experience lots of collision in a short time causing high air pressure

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2
Q

Atmospheric pressure is caused by

A

the weight of the column of air molecules in the atmosphere above an objet

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3
Q

Pressure can be increased by (Not temp or volume) (2)

A

increasing force or decreasing the area

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4
Q

In terms of weather, low-pressure systems occur when (2)

A

the earths atmospheric pressure is lower than the surrounding environment

moist air rises and condenses producing clouds

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5
Q

as you go up the troposphere (3)

A

air density, air pressure and temp decrease

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6
Q

hydrostatic pressure

A

pressure by a fluid due to gravity

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7
Q

Ideal gas

A

a hypothetical construct that real gases approximate under certain conditions

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8
Q

effects of temp on the volume of a given amount of a confined gas at constant pressure

A

the volume increases as the temp increases and decrease as the temp decreases

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9
Q

This relationship between temperature and pressure is observed for any sample of gas confined to a constant volume

not go up and down

A

Temperature and pressure are linearly related and proportional is temp is in Kelvin

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10
Q

Boyle’s Law

A

The volume of a given amount of gas held at constant temp is inversely porprotional to the pressure under which it is measured

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11
Q

If volume increase by a certain factor, the pressure will_____ assuming ____ and _____ do not change

A

decrease by the same factor

moles and temp

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12
Q

Tell me how breathing works with the lungs and shit

A

Breathing occurs because the expanding and contracting of your lungs causes air pressure difference causing air to be drawn into and forced out

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13
Q

Avogadros law

A

For a confined gas the volume and number of moles are proportional if the pressure and temp remain the same

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14
Q

ideal gas law (3)

A

combining all the laws with p,v,,n,t

Pv=nRT

describes gas under ideal conditions

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15
Q

ideal conditions of gas us holds true to real life when conditions are:

A

gas is under low pressure and high temp

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16
Q

combined gas law when moles are the same

A

P1V1/T1=P2V2/T2

17
Q

Combined gas law when moles are different

A

P1V1/n1T1=P2V2/n2T2

18
Q

If the number of moles of an ideal gas are kept constant under two different sets of conditions, a useful
mathematical relationship called the combined gas law. In the combined gas law, both sets of conditions are equal to the product of….

A

moles(R)

nR

19
Q

general units for combined gas law

A

atm, K, L

20
Q

standard temperature and pressure

A

1 mole of an ideal gas have v=22.4L

p=1atm

T=273.15K

21
Q

Difference between density and ideal gas law

A

Density is an characteristic determined by its identity

ideal gas law relates these properties in identical fashion regardless of the chemical identity of the gas

22
Q

density formula

A

d= (molar mass)(p)/(RT)

23
Q

Daltons’s Law of partial pressures+ equation

A

The total pressure of a mixture of ideal gases is equal to the sum of the partial pressures of the component gases

Ptotal= Pa+Pb+Pc….

24
Q

Each individual gas in a mixture exerts

A

the same pressure that it would exist if it were present alone in the container

25
Q

the coefficient infront of the chemical equation signifies

A

the moles which is also equal to the volume

26
Q

Kinetic molecular theory which one describes amonton law?

A

If the temperature is increased, the average speed and kinetic energy of the gas molecules increase. If the volume is held constant, the increased speed of the gas molecules results in more frequent and more forceful collisions with the walls of the container, therefore increasing the pressure

27
Q

Kinetic molecular theory which one describes Charles law?

A

If the temperature of a gas is increased, a constant pressure may be maintained only if the volume occupied by the gas increases. This will result in greater average distances traveled by the molecules to reach the container walls, as well as increased wall surface area. These conditions will decrease the both the frequency of molecule-wall collisions and the number of collisions per unit area, the combined effects of which balance the effect of increased collision forces due to the greater kinetic energy at the higher temperature.

28
Q

Kinetic molecular theory which one describes Boyles law?

A

If the gas volume volume of a given amount of gas at a given temperature is decreased (that is, if the gas is compressed), the molecules will be exposed to a decreased container wall area. Collisions with
the container wall will therefore occur more frequently and the pressure exerted by the gas will increase

29
Q

The average speed of a gas depend

A

its molar mass—the lighter the mass, the faster the average speed.

30
Q

speed of particles in a gas sample

not mass related one

A

individual molecules have varying speed but the molecular speed distribution (after an hour the curve is still the same) and average speed is constant (after 1 hour average speed is still the same).

31
Q

Maxwell-Boltzmann

A

depicts the relative numbers of molecules in a bulk sample of gas that possesses a given speed

32
Q

if temp of a gas increases,……+effect of the Maxwell-Boltzmann graph

A

its KE value also increase, more molecules have higher speeds and fewer molecules have lower speeds, and the distribution shifts toward higher speeds overall, that is, to the right.

33
Q

Gases composed of lighter molecules have more…..+speed distribution (2)

A

high-speed particles

with a speed distribution that peaks at relatively higher speeds

34
Q

Gases consisting of heavier molecules have more….+speed distribution (2)

A

more low-speed particles

a speed distribution that peaks at relatively lower speeds.

35
Q

compressibility factor (Z)+ how do you know ideal gas law not accurate (2)

A

molar volume of gas at same temp+pressure/molar volume of ideal gas at same temp+pressure

any deviation from 1 is an indication of non-ideal behavior

36
Q

when does ideal gas law fail

A

at relatively high pressures

37
Q

how do real gas behaviour fail at Boyle’s law?

A

Boyles law states that as pressure increase, volume decrease.

gas forces in-between will decrease volume like suppose to but also decrease pressure which should have increased even more since u have this extra volume decrease

However, when the gases are crowded tgt with high pressure and low volume, they start sticking to eachother this decreases the pressure (if the volume is constant) or decreasing the volume (at constant pressure) (Figure 9.36). This change is more pronounced at low temperatures because the molecules have lower KE relative to the attractive forces, and so they are less effective in overcoming these attractions after colliding with one another.