thermodynamics Flashcards
What is Lattice enthalpy of formation
The enthalpy change when 1 mole of a solid ionic compound is formed from its gaseous ions
What is Lattice dissociation enthalpy
The enthalpy change when 1 mole of a solid ionic compound is completely dissociated into its gaseous ions
What is Enthalpy change of solution
When one mole of a solid ionic substance dissolves in water to produce aqueous ions in an infinitely dilute solution
What is Enthalpy change of hydration
The enthalpy change when 1 mole of aqueous ions is formed from gaseous ions
what factors affect enthalpy of hydration
the partial negatives and positives of the water are attracted to the ions
the smaller the ion the more strongly attracted to the partial charges of the water molecules are to the ions the larger the enthalpy of hydration
what is the definition of the enthalpy of atomisation
when the elements in their standard states form one mole of gaseous ions
what factors can produce covalent character
small highly charged positive ions in the lattice
large highly charged negative ions
what properties does covalent character affect
the solubility (less) and the conductive ability (less)
what is entropy
the measure of disorder or randomness in a system
factors that affect entropy
- state matter
- energy of the particles
- dissolving the substance
- number of particals
when is a reaction feasible
when the delta G=0
what is ionisation energy
the amount of energy required to remove one mole of electrons from one mole of gaseous ions
what is enthalpy of atomisation
enthalpy change when 1 mole of gaseous atoms is formed from its element under standard conditions