thermodynamics Flashcards

1
Q

What is Lattice enthalpy of formation

A

The enthalpy change when 1 mole of a solid ionic compound is formed from its gaseous ions

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2
Q

What is Lattice dissociation enthalpy

A

The enthalpy change when 1 mole of a solid ionic compound is completely dissociated into its gaseous ions

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3
Q

What is Enthalpy change of solution

A

When one mole of a solid ionic substance dissolves in water to produce aqueous ions in an infinitely dilute solution

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4
Q

What is Enthalpy change of hydration

A

The enthalpy change when 1 mole of aqueous ions is formed from gaseous ions

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5
Q

what factors affect enthalpy of hydration

A

the partial negatives and positives of the water are attracted to the ions

the smaller the ion the more strongly attracted to the partial charges of the water molecules are to the ions the larger the enthalpy of hydration

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6
Q

what is the definition of the enthalpy of atomisation

A

when the elements in their standard states form one mole of gaseous ions

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7
Q
A
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8
Q

what factors can produce covalent character

A

small highly charged positive ions in the lattice

large highly charged negative ions

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9
Q

what properties does covalent character affect

A

the solubility (less) and the conductive ability (less)

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10
Q

what is entropy

A

the measure of disorder or randomness in a system

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11
Q

factors that affect entropy

A
  1. state matter
  2. energy of the particles
  3. dissolving the substance
  4. number of particals
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12
Q

when is a reaction feasible

A

when the delta G=0

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13
Q

what is ionisation energy

A

the amount of energy required to remove one mole of electrons from one mole of gaseous ions

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14
Q

what is enthalpy of atomisation

A

enthalpy change when 1 mole of gaseous atoms is formed from its element under standard conditions

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15
Q
A
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