thermodynamics Flashcards

1
Q

what is thermodynamics

A

direction of processes

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2
Q

what are the three types of system

A

isolated, closed and open

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3
Q

what is the first law of thermodynamics

A

energy cannot be created or destroyed only moved/transferred/converted

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4
Q

what does the first law of thermodynamics ignore

A

preferred direction of a reaction

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5
Q

what is the surroundings

A

the rest of the universe inContact to a system

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6
Q

what is a system

A

a part of the universe being focused on

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7
Q

what can closed systems do

A

exchange energy to the surrounding but not matter

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8
Q

what can an isolated system do

A

it cannot exchange either matter or energy

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9
Q

what can an open system do

A

exchange both energy and matter

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10
Q

what is energy

A

a state of function that depends on the state of the system not the process of how the system got to the state

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11
Q

what are the two types of energy

A

heat (q) energy transferred by random motion

work (w) energy transferred by organised motion

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12
Q

what is enthalpy change

A

the heat change of a reaction at a constant pressure

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13
Q

what does enthalpy change reflect

A

the number and types of chemical bonds in reactants and products

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14
Q

what can enthalpy change be used for

A

direct measure of energy change

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15
Q

what is the second law of thermodynamics

A

a spontaneous change in a system that occurs in a direction that increases the combined entropy of the universe to increase

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16
Q

what is change in system + change in surroundings equal to

A

= change in universe> 0

17
Q

entropy means

A

a state of function of randomness and disorder in a system

18
Q

How is a reaction feasible

A

if free energy is negative

19
Q

if gibbs free energy is zero…

A

reaction is at equilibrium

20
Q

what does gibbs depend on

A

amount of material in a system

21
Q

G>0

A

forward reaction is energetically unfavourable, requires energy to occur

reverse reaction occurs spontaneously

22
Q

G=0

A

no further change-> equilibrium

23
Q

G<0

A

forward reaction is energetically favourable so forward reaction occurs spontaneously

24
Q

what does entropy measure

A

degree of disorder/randomness

25
Q
A