thermodynamics Flashcards

1
Q

entropy of surroundings equation

A

-ΔH/T = ΔS Surroundings

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2
Q

Gibbs equation

A

ΔG = ΔH - TΔS(sur)

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3
Q

thermochemical definition

A

quantity used to define whether a reaction tends to go and how far it will go. If negative, reaction is feasible

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4
Q

what is a spontaneous reaction

A

ΔS(tot) is positive for spontaneous

a process which occurs without input of matter or electrical energy into the system

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5
Q

Table of reaction type

A

EXO - INC - (-) FEASIBLE
EXO - DEC - (+) - FEASIBLE IF ΔH > TΔS
ENDO - INC - (+) - FEASIBLE IF ΔH < TΔS
ENDO - DEC - (+) - NOT FEASIBLE

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6
Q

what is standard molar entropy

A

the entropy or degree of randomness of one mole of a sample under standard state conditions

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7
Q

Total entropy equation

A

ΔH(tot) = ΔS(sur) + ΔS(sys)

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8
Q

entropy of a system equation

A

ΔS(sys) = S(prod) - S(reac)

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9
Q

what are the conditions for Gibbs to work

A

needs to be negative

want the exothermic to be more negative than system

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