thermodynamic definitions Flashcards
enthalpy of atomisation (solid to gas)
the enthalpy change when 1 mole of gaseous atoms is formed from the element in its standard state
bond dissociation enthalpy (Cl2 (g)»_space;> 2Cl (g)
Enthalpy change when 1 mole of covalent bonds is broken into 2 gaseous atoms
first electron affinity (O (g) + e- >. O- (g) )
the enthalpy change when 1 mole of gaseous atoms gain 1 mole of electrons to form 1 mole of gaseous 1- ions
Enthalpy lattice of formation (Na+ (g) + Cl- (g)»_space;> NaCl (s))
Enthalpy change when 1 mole of solid ionic compound is formed from its constituent ions in the gas phase.
Enthalpy lattice of dissociation (NaCl (s)»_space; Na+ (g) + Cl- (g) )
Enthalpy change when 1 mole of solid ionic compound is broken up into its constituent ions in the gas phase.
enthalpy of hydration (X+(g) + aq+»_space;> X+(aq) )
Enthalpy change when one mole of gaseous ions become aqueous ions . (attraction between metal ion and Oδ- of water)
enthalpy of solution (NaCl (s)»_space;> Na+ (aq) + Cl-(aq)
enthalpy change when one mole of a solid ionic compound dissolves in a amount of water large enough to ensure that the dissolved ions are well separated and don’t interact with one another