Thermochemistry Definitions Flashcards
Thermochemistry
The study of the energy changes that accompany physical or chemical changes
Chemical system
A group of reactants and products being studied
Energy
The ability to do work; SI units joules (J)
Work
The amount of energy transferred by a force over a distance; SI units joules (J)
Heat
The transfer of thermal energy from a warm object to a cooler object
Temperature
A measure of the average kinetic energy of entities in a substance
Potential Energy
The energy of a body or system due to its position or composition
Kinetic Energy
The energy of an object due to its motion
Standard State
The most stable form of a substance under standard conditions, 25 degrees and 100 kPa
Standard Enthalpy of Formation (ΔHf0)
energy associated with 1 mole, formed from its elements in standard states
Open System
a system in which both matter and energy are free to enter and leave the system
Potential Energy Diagram
A graphical representation of the energy transferred during a physical or a chemical change
Bond Dissociation Energy
The energy required to break a given chemical bond
Molar Enthalpy Change (ΔHx)
The enthalpy change associated with a physical, chemical, or nuclear change involving 1 mol of a substance; SI units J/mol
Endothermic
absorbing energy from the surroundings
Closed System
a system in which energy can enter or leave, but matter cannot
Surroundings
all matter that is not part of the system
Enthalpy Change (ΔH)
The energy released to or absorbed from the surroundings during a chemical or physical change
Calorimeter
a device that is used to measure thermal energy changes in a chemical or physical change
Isolated System
an ideal system in which neither matter nor energy can move in or out
Calorimetry
the experimental process of measuring the thermal energy change in a chemical or physical change
Exothermic
Releasing energy to the surroundings
Thermal Energy
The total quantity of kinetic and potential energy in a substance
Law of Conservation of Energy
Energy cannot be created or destroyed