Thermochemistry Definitions Flashcards

1
Q

Thermochemistry

A

The study of the energy changes that accompany physical or chemical changes

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2
Q

Chemical system

A

A group of reactants and products being studied

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3
Q

Energy

A

The ability to do work; SI units joules (J)

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4
Q

Work

A

The amount of energy transferred by a force over a distance; SI units joules (J)

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5
Q

Heat

A

The transfer of thermal energy from a warm object to a cooler object

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6
Q

Temperature

A

A measure of the average kinetic energy of entities in a substance

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7
Q

Potential Energy

A

The energy of a body or system due to its position or composition

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8
Q

Kinetic Energy

A

The energy of an object due to its motion

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9
Q

Standard State

A

The most stable form of a substance under standard conditions, 25 degrees and 100 kPa

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10
Q

Standard Enthalpy of Formation (ΔHf0)

A

energy associated with 1 mole, formed from its elements in standard states

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11
Q

Open System

A

a system in which both matter and energy are free to enter and leave the system

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12
Q

Potential Energy Diagram

A

A graphical representation of the energy transferred during a physical or a chemical change

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13
Q

Bond Dissociation Energy

A

The energy required to break a given chemical bond

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14
Q

Molar Enthalpy Change (ΔHx)

A

The enthalpy change associated with a physical, chemical, or nuclear change involving 1 mol of a substance; SI units J/mol

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15
Q

Endothermic

A

absorbing energy from the surroundings

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16
Q

Closed System

A

a system in which energy can enter or leave, but matter cannot

17
Q

Surroundings

A

all matter that is not part of the system

18
Q

Enthalpy Change (ΔH)

A

The energy released to or absorbed from the surroundings during a chemical or physical change

19
Q

Calorimeter

A

a device that is used to measure thermal energy changes in a chemical or physical change

20
Q

Isolated System

A

an ideal system in which neither matter nor energy can move in or out

21
Q

Calorimetry

A

the experimental process of measuring the thermal energy change in a chemical or physical change

22
Q

Exothermic

A

Releasing energy to the surroundings

23
Q

Thermal Energy

A

The total quantity of kinetic and potential energy in a substance

24
Q

Law of Conservation of Energy

A

Energy cannot be created or destroyed

25
Q

Hess’s Law

A

The enthalpy change for the conversion of reactants to products is the same whether the conversion occurs in one step or several steps

26
Q

Exothermic Reaction example

A

Exothermic reaction is where energy is released into the surroundings as indicated by the lower level in the diagram. An example of an exothermic reaction is the burning of a candle where the bonds between hydrocarbons are broken releasing energy as heat into the surroundings

27
Q

Endothermic Reaction example

A

Endothermic reaction is when energy is absorbed from the surroundings indicated by the higher energy level. An example is cooking an egg where the pan absorbs the heat from the stove to begin cooking the egg

28
Q

Exothermic Chemical reaction example

A

An example of an exothermic chemical reaction is the combustion of magnesium where the product of the chemical reaction is magnesium oxide as energy is released into the surroundings through the combustion

29
Q

Endothermic Chemical reaction example

A

An example of an endothermic chemical reaction is the decomposition of water into its elements of hydrogen and oxygen