Thermochemistry Flashcards

1
Q

capacity to do work

A

energy

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2
Q

chemistry defined - as directed energy change resulting in process

A

work

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3
Q

energy that comes from the sun and is earth’s primary energy source

A

radiant energy or solar energy

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4
Q

energy associated with the random motion of atoms and molecules

A

thermal energy

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5
Q

energy stored within structural units of chemical substances

A

chemical energy

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6
Q

energy available by virtue of an objects position

A

potential energy

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7
Q

the transfer of thermal energy between 2 bodies that are at different temperatures

A

heat

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8
Q

the study of heat change in chemical reactions

A

thermochemistry

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9
Q

the specific part of the universe that is of interest to us

A

system

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10
Q

the rest of the universe outside a system

A

surrounding

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11
Q

can exchange mass and energy, usully in the form of heat with its surroundings

A

open system

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12
Q

allows the transfer of energy (heat) but not mass

A

closed system

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13
Q

does not allow the transfer of either mass of energy

A

isolated system

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14
Q

properties that are determined by the state of the system, regardless of how that condition was achieved; only the start and end points matter rather than the path taken

A

state functions

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15
Q

the first law of thermodynamics

A

energy can be converted from one form to another but cannot be created or destroyed

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16
Q

energy that is transferred from one body to another as the result of a difference in temperature

A

heat (q)

17
Q

energy transferred to or from an object via the application of force along a displacement

A

work (w)

18
Q

the unit for work done by or on a gas is -

A

liter atmospheres

19
Q

1 L atm = ?

A

101.3 J

20
Q

when a process occurs at a constant pressure, the heat evolved (released or absorbed) is equal to the -

A

change in enthalpy

21
Q

it is the sum of internal energy and the product of pressure and volume

A

enthalpy

22
Q

who developed hess law

A

germain hess

23
Q

it is based on the idea that energy is conserved and cannot be created or destroyed

A

hess law

24
Q

hess law states that

A

the enthalpy change of a chemical reaction is independent of the path taken