Thermochemistry Flashcards
What is the study of energy changes that occur during chemical reactions?
thermochemistry
Thermal energy is an ex of _______
kinetic energy
What is the first law of thermodynamics?
energy can not be created or destroyed only transformed
What is internal energy?
ΔE
q=
heat
w=
work
An endothermic process has …
+E and +q
An exothermic process has ….
=E and -q
work/w=
PΔV
+w is (+p)
compression
-w is (-p)
expansion
What is total energy?
ΔH
H=E+PV
Total energy
Coffee cup calorimetry has …
constant pressure
eqn for calorimety is
q=msΔT
if change in T for cal is +
rxn q is -
qrxn=
-qcal/soln
A bomb calorimeter has …
constant volume
for bomb calorimetry use the eqn
q=sΔT
more complex molecule/ system has _________ heat capacity
higher