Thermo Lecture 1 Flashcards

1
Q

What are the 2 manifestations of energy?

A
  1. Can be freely and fully converted into other types

2. Thermal. Cannot be fully converted

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2
Q

What is ‘Energy Dissipation’?

A

The conversion of non-thermal energy to heat

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3
Q

What is the Equation for work?

A
  1. dW = F dx

2. dW = -PdV

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4
Q

What are the units of work?

A

J

kg m^2 s^-2

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5
Q

What is an open system?

A

Where mass transfer can occur between the system & surroundings

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6
Q

What is a closed system?

A

Where there is NO mass transfer but energy can flow as work or heat

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7
Q

What is an isolated system?

A

Where there is no mass or energy transfer

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8
Q

What is expansion work?

A

Energy transfer that has resulted in a change of volume. The expanding substance is going mechanical work on its surroundings

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9
Q

What is a reversible process?

A

One which moves through a series of equilibrium states and therefor is no energy dissipation (as head) as the process proceeds

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10
Q

What does ‘quasi-static’ mean?

A

Proceeding though a series of equilibrium states, reaction is slow enough to keep system in internal equilibrium

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11
Q

What is an adiabatic system?

A

A process or system in which no heat is transferred between system and surroundings. No energy dissipation.

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12
Q

What is the Ideal Gas EOS

A

PV = nRT

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13
Q

What are the assumptions of the Ideal Gas EOS?

A
  1. Vol occupied by molecules &laquo_space;Vol occupied by gas
  2. No intermolecular forces
  3. Collisions between molecules elastic
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14
Q

Equation for Kt?

A

Kt = -V(dP/dV)t

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15
Q

Equation for βt?

A

1/Kt

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16
Q

Equation for α?

A

1/V(dV/dT)p

17
Q

Define ‘phase’?

A

The physically distinguishable subsets of a system

18
Q

Define ‘extensive’ properties

A

Properties dependent on the amount of a substance

19
Q

Define ‘intensive’ properties

A

Properties independent on the amount of a substance e.g. P & T

20
Q

What are state functions?

A

Properties that define the state of a system?

They are independent of path, are exact differentials and are in a closed cycle.

21
Q

What is Heat Capacity, C?

A

C = dQ/dT

The heat absorbed by a system over the resultant temperature rise

22
Q

Why does a system of constant volume yield a greater temperature increase than one with constant pressure ?

A

Because when constant P some heat used for expansion work in addition to temperature rise

23
Q

What does the zeroth Law of Thermodynamics state?

A

T is a state function