Thermo Flashcards

1
Q

Work

A

dW = Fdl

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2
Q

Potential Energy

A

PE = (mgz)/ gc

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3
Q

Kinetic Energy

A

KE = (mv^2)/2gc

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4
Q

Work in fluid system

A

dW = -PdV

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5
Q

Ideal Gas Constants (R)

A

8.314 J/mol K or Pa m3/mol K
0.08205 L atm/mol K
1.987 cal/mol K
10.73 ft3 psi/lbmol R
0.73 ft3 atm/lbmol R

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6
Q

Work done on the system

A

Endergonic

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7
Q

Work done by the system

A

Exergonic

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8
Q

Heat absorbed by the system

A

Endothermic

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9
Q

Heat release by the system

A

Exothermic

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10
Q

Gibbs Phase Rule

A

F = 2 - pi + N

pi - # of phases (liq solid gas)
N - # of components (water, alcohol etc)

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11
Q

Joule’s Experiment

A

Win = Qout
delta PE = mCp(deltaT)

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12
Q

Heat Capacity Cp water

A

4.184 kJ/kg K
1 BTU/lbm F

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13
Q

Internal Energy

A

delta U = Q + W

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14
Q

Enthalpy

A

delta H = delta U + delta (PV)
dH = dU + d(PV)

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15
Q

Heat Capacity C

A

C = dQ/dT

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16
Q

Isochoric (V=k)

A

W = 0
Cp = dU/dT
Q = delta U = integral CvdT

17
Q

Isobaric (P=k)

A

W = -PdV = -RdT (for ideal gas)
Q = delta H = integral CpdT

18
Q

Introduced Zeroth Law of Thermodynamics

A

Ralph Howard Fowler

19
Q

State that exists between two subsystems of equal temperature

A

Thermal Equilibrium

20
Q

Introduced the First Law of Thermodynamics

A

Rudolf Julius Emmanuel Clausius

21
Q

Energy conserved after the transfer of heat or work

A

Internal Energy

22
Q

Energies in transit. Only exists when energy is being transferred from one system to the next

A

Heat and Work

23
Q

Functions that depend on the current state of the system and not on how the system reaches that state

A

State / Point Function

H S T P V

24
Q

Functions that depend on the path followed during the process

A

Path Function

W Q

25
Q

Closed System Energy Balance (Non-flow)

A

delta U = Q + W

26
Q

Open System Energy Balance (Steady Flow)

A

delta H + delta PE + delta KE = Q + Ws

27
Q

Isothermal (T=k)

A

W = RT ln(V1/V2)
= RT ln(P2/P1)
Q = -W
delta U = 0
delta H = 0

28
Q

Adiabatic

A

Q = 0
W = delta U

29
Q

Pump Work

A

Wact = W/eff

30
Q

Turbine Work

A

Wact = W x eff

31
Q

Density of Water

A

1000 kg/m3
62.4 lb/ft3