Thermal Physics (topic 3) Flashcards
Heat
Transfer of energy between a system and its surroundings.
Q = heat (J)
Temperature
Average kinetic energy of the molecules. Larger velocities -> larger Ek. Faster particles -> hotter
T = temperature (°C or K)
Internal energy
Total kinetic energy plus potantial energy.
U = internal energy (J)
Specific heat capacity
Energy needed to raise the temperature of one unit of mass of material by 1K
Q = mcΔT
where
Q = heat (J)
m = mass (kg)
c = specific heat capacity (J kg^-1 °C^-1)
ΔT = change in temperature (°C or K)
Heat gained = heat lost
Specific latent heat
Energy per unit mass absorbed or released during a phase change.
Q = mL (use for every phase change)
where
Q = heat (J)
m = mass (kg)
L = specific latent heat (J kg^-1)
Ideal gas
- No forces between molecules
- must work for all pressures volumes and temperatures
Pressure
p = force / area
**If volume gets smaller, pressure increases
Ideal gas law
pV = nRT
where
p = pressure (Pa)
V = volume (m^3)
n = number of moles
R = gas constant (J mol^-1 K^-1)
T = temperature (K)
Gas laws
- Constant volume
- Charles’ law
- Boyle’s law
Constant volume
pV = nRT; v = constant
p is proportional to T. As temperature goes up, pressure goes up
In a graph: straight slope from the origin
Charles’ law
pV = nRT; p = constant
V is proportional to T. As temperature goes up, volume goes up
In a graph: straight slope from the origin
Boyle’s law
pV = nRT; T = constant
p is proportional to 1/V
In a graph: a negative exponential graph
Moles and Avogadro
n = N / Na
where
n = number of moles
N = number of atoms
Na = Avogadro’s constant
Power equation
P = ΔE / Δt
where,
P = power
ΔE = change in energy
Δt = change in time
Kinetic model of an ideal gas
Intermolecular forces are negligible.
Therefore, a real gas may be approximated by that of an ideal gas under the following conditions as they all reduce effect of intermolecular forces.
- the gas density is low - gas particles are far apart
- pressure is low - gas particles are far apart
- temperature is high - gas particles move more quickly