Thermal Physics Flashcards

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1
Q

Internal energy of an object

A

The sum of the random distribution of the kinetic and potential energies of its molecules.

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2
Q

First law of thermodynamics

A

The change of internal energy of the object = the total energy transfer due to work done and heating.

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3
Q

Solid

A

The atoms and molecules are held to each other by forces due to the electrical charge of the protons and electrons in the atoms. Molecules vibrate randomly about fixed positions.

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4
Q

Liquid

A

The moelcules move about at random in contact with each other. The forces between the molecules are not strong enough to hold the molecules in fixed positions.

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5
Q

Gas

A

The molecules also move about randomly but much further apart on average than in a liquid.

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6
Q

Thermal equilibrium

A

A state of a system in which all parts are at the same temperature.

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7
Q

Ice point

A

0 degrees celsius

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8
Q

Steam point

A

100 degrees celsius

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9
Q

Absolute zero

A

0 K

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10
Q

Triple point of water

A

273.16 K

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11
Q

Temperature in celsius

A

Absolute temperature in kelvins - 273.15

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12
Q

Absolute zero definition

A

The lowest possible temperature, an object at absolute zero has minimum internal energy.

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13
Q

Specific heat capacity, c, of a substance

A

The energy needed to raise the temperature of unit mass of the substance by 1 K without change of state.

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14
Q

The unit of specific heat capacity

A

J kg^-1 K^-1

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15
Q

The energy needed to raise the temperature of a substance of mass, m from T1 to T2

A

ΔQ = mc (T2 - T1)

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16
Q

Sublimation

A

The process by which some solids vaporise directly when heated.

17
Q

The specific latent heat of fusion, l, of a substance

A

The enegy needed to change the state of unit mass of the substance from solid to liquid without change of temperature.

18
Q

The specific latent heat of vaporisation of a substance

A

The energy needed to change the state of unit mass of the substance from liquid to vapour without any change of temperature.

19
Q

The energy, Q, needed to change the state of mass, m, of a substance from liquid to vapour without change of temperature.

A

Q = m x l

20
Q

Pressure of a gas definition

A

The force per unit area that the gas exerts normally on a surface.

21
Q

Boyle’s law

A

pV =constant

22
Q

Isothermal change

A

Change at constant temperature.

23
Q

Isobaric change

A

Change at constant pressure.

24
Q

Charle’s law

A

V/T = constant

25
Q

Work done by a gas on a piston

A

p ΔV

26
Q

The pressure law

A

p/T = constant

27
Q

Brownian motion

A

Term used to describe the motion of individual molecules in a gas.

28
Q

The Avogrado constant, NA

A

6.023 x 10^23, the number of atoms in exactly 12g of the carbon isotope 12C6.

29
Q

Definition of one mole

A

The quantity of substance that contains NA particles. Unit is the mol.

30
Q

The molar mass of a substance

A

The mass of 1 mol of the substance.

31
Q

An ideal gas

A

A gas that obeys Boyle’s law, the three experimental gas laws can be combined to give the equation pV/T - constant, for a fixed mass of ideal gas.

32
Q

Ideal gas equation

A

pV = nRT

33
Q

Molar gas constant, R

A

8.31 J K^-1 mol^-1

34
Q

Boltzmann constant, k

A

1.38 x 10^-23 J K^-1

35
Q

Kinetic theory equation

A

pV = 1/3 N m (Crms)^2

36
Q

Assumptions made about molecules in gas

A

The volume of each molecule is negligible compared with the volume of the gas. Molecules do not attract eachother and move about in continual random motion. Collisions are elastic.

37
Q

Kinetic energy of gas molecule

A

1/2 m (Crms)^2 = 3/2 k T = 3RT/2NA