Thermal Physics Flashcards

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1
Q

What is the internal energy equal to

A

The sum of all the kinetic energies and potential energies of all its particles

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2
Q

How are all the kinetic energies and potential energies distributed in a body

A

Randomly distributed

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3
Q

What are the two ways you can increase the internal energy of a system

A
  • do work on the system to transfer energy to it (e.g moving its particles/changing its shape)
  • increase the temperature of the system
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4
Q

What happens to the internal energy as the state of the substance changes

A

The internal energy also changes

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5
Q

Why does the internal energy change when when the substance exchanges state

A

The potential energy of the system changes while the kinetic energy of the system is kept constant

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6
Q

How can we demonstrate that if a substance changes state the internal energy also changes

A

By measuring the temperature id water as it boils
- the temperature increases up until 100 degrees Celsius after which the energy gained through heating the water is no longer used to increase the temperature ( and therefore the kinetic energy) but instead is used to break bonds between water molecules so it can change state to water vapour and so the potential energy is increased

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7
Q

What equation can you use to measure the amount of energy required to change the temperature of a substance

A

Q = m x c x change in temp Q=energy required m=mass c=specific heat capacity

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8
Q

What is the definition of specific heat capacity

A

Is the amount of energy required to increase the temperature of 1kg of a substance by 1 degree Celsius/1k without changing state

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9
Q

What equation can be used to measure the amount of energy required to change the state of a substance

A

Q = m x l Q=energy required m=mass l=specific latent heat

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10
Q

What is the definition of specific latent heat

A

The amount if energy required to change the state of 1kg of material, without changing its temperature

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11
Q

What are the two types of specific latent heat

A

Specific latent heat of fusion ( when solid changes to liquid )
Specific latent heat of vaporisation ( when liquid changes to gas )

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12
Q

What do the gas laws describe

A

The experimental relationship between pressure volume and temperature for a fixed mass of gas

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13
Q

Are the laws based on a theory or from observation and experimental evidence

A

From observation and experimental evidence which means they are empirical in nature

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14
Q

What are the three laws

A

1 - Boyle’s law
2 - Charles’ law
3 - The pressure Law

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15
Q

What is Boyle’s and it’s equation

A

When temperature is a constant and pressure and volume are inversely proportional
PV = K

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16
Q

What is Charles’ law and its equation

A

When pressure is a constant, volume is directly proportional to absolute temperature
V/T = K

17
Q

What is the pressure law and its equation

A

When volume is constant, pressure is directly proportional to absolute temperature
P/T = K

18
Q

What temperature measured in when using the gas laws

A

Kelvin

19
Q

What is the value of absolute zero

A

0K = -273°C

20
Q

What happens to particles when they reach absolute zero and what happens to a gas

A

They have no kinetic energy and the volume and pressure of a gas are zero

21
Q

What equation do you get when you combine all the laws of gas

A

PV/T = K

22
Q

What dies K equal to in the equation PV/T = K and what is the rearranged equation

A

K = nR where n is the number of moles and R is the molar gas constant and the new equation is PV = nRT

23
Q

What is the value of the molar gas constant

A

8.31

24
Q

What is the value of 1 mole of a substance

A

6.02 x 10^23 atoms/molecules

25
Q

What is the equation to covert between the number of moles and the number of molecules

A

N = n x Na N=the number of molecules n = the number of moles Na= the Avogadros constant

26
Q

What are the two ideal gas equations

A

PV= nRT and PV= NkT
N is the number of molecules
K is the Boltzmann constant

27
Q

What is the molar mass and how can it be found

A

Is the mass ( in grams ) of one mole of a substance and can be found by finding the relative molecular mass which is approx equal to the sum of all the nucleons in a molecule of the substance

28
Q

What is the equation used to calculate work done on a gas to change its volume when it’s at constant pressure ( this is usually done through the transfer of thermal energy)

A

Work done = p x change in V
P = pressure
V = volume

29
Q

How do you find the work done on a pressure volume graph

A

The area under the graph

30
Q

what is Brownian motion

A

is the random motion of larger particles in a fluid caused by collisions with surrounding particles

31
Q

how can Brownian motion be observed

A

looking through at smoke particles under a microscope

32
Q

what did Brownian motion contribute evidence to

A

the existence of atoms and molecules

33
Q

how can you use the simple molecular model to explain Boyle’s law

A

if you increase the volume of a fixed mass of gas, its molecules will move further apart so collisions will be less frequent therefore pressure decreases

34
Q

how can you use the simple molecular model to explain Charles’ law

A

when the temp of a gas is increased, its molecules gain kinetic energy meaning they will move more quickly and because pressure is kept constant the molecules move further apart and volume is increased

35
Q

how can you use the simple molecular model to explain pressure law

A

when the temp of a gas is increased, its molecules gain kinetic energy meaning they will move more quickly, as a volume is constant the frequency of collisions between molecules and their container increases and they collide at higher speeds therefore pressure is increased

36
Q

what does empirical in nature mean

A

they are not based on a theory but arose from observation and experimental evidence

37
Q

what are the 5 assumptions made in the molecular kinetic theory

A
  • no intermolecular forces act on the molecules
  • the duration of collisions is negligible in comparison to time between collisions
  • the motion of molecules is random, and they experience perfectly elastic collisions
  • the motion of the molecules follow newtons laws
  • the molecules move in straight lines between collisions