Thermal Flashcards

1
Q

Probability of a state

A
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2
Q

Partition β

A

β = 1 / (kT)

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3
Q

Partition function

A
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4
Q

Expectation value of energy (full formula)

A
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5
Q

Expectation value of energy (partition shortcut)

A
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6
Q

Entropy in terms of multiplicity

A

S = k lnΩ

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7
Q

Entropy, given probability of microstates

A
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8
Q

Shortcut entropy expression for monotomic ideal gas

A
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9
Q

Classical limit of the partition function

A
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10
Q

Binomial coefficient

A
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11
Q

Sterling’s formula

A
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12
Q

1st law of thermal

A

ΔU = Q - W

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13
Q

2nd law of thermal

A
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14
Q

Work in a reversible process

A

δW = P dV

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15
Q

Differential form of entropy change of a system undergoing a reversible process

A

δQ = T dS

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16
Q

Integral form of entropy change of a system undergoing a reversible process

A
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17
Q

Fundamental thermodynamic identity

A

dU = TdS - PdV

18
Q

Temperature given by the fundamental thermodynamic identity

19
Q

Pressure given the fundamental thermodynamic identity

20
Q

Energy Maxwell relation

21
Q

Heat capacity at constant volume

22
Q

Heat capacity at constant pressure

23
Q

Differentiation of the fundamental thermodynamic identity with respect to T

24
Q

Difference of heat capacities of an ideal gas

A

CP - CV = Nk

25
Change in temperature
Q = mcΔT
26
Heat engine efficiency
27
Maximum efficiency of a heat engine
28
Internal energy of a classical ideal gas
29
vrms
30
Speed of sound in an ideal gas, given pressure and density
31
Speed of sound in an ideal gas, given temperature and mass
32
Fermi-Dirac distribution
33
Bose-Einstein distrubtion
34
Average number of fermions/bosons
35
Approximation of average number of fermions/bosons if energy levels are spaced closely together
36
γ
(f+2) / f
37
Monotomic molecule degrees of freedom
3 translational, f=3
38
Diatomic molecule degrees of freedom
3 translational, 2 rotational, 2 vibrational, f = 5 +2b b=0 at room temperature b=1 at high temperatures
39
Polyatomic molecule degrees of freedom
3 translational, 3 rotational, 2N vibrational, f=6+2N N=number of atoms
40
Solid degrees of freedom
3 vibrational in each kinetic and potential energy f=6