The Structure of Crystalline Solids Flashcards
material is one in which the atoms are situated in a repeating or
periodic array over large atomic distances—that is, long-range order exists
Crystalline
the material, the manner in which atoms, ions, or molecules are spatially arranged.
Crystal structure
constituent particles are not arranged in any regular fashion; they may be at the most some short range order
amorphous solid
constituent particles are arranged in any regular fashion, containing short range order as well as long range order
Crystalline Solids
is used in the context of crystal structures; means a three-dimensional array of points coinciding with atom positions (or sphere centres).
Lattice
Three relatively simple crystal structures are found
for most of the common metals
1.) face-centered cubic (FCC) crystal structure
2.) body centered cubic (BCC) crystal structure
3.) hexagonal close-packed (HCP) crystal structure
It contains 4 atoms in a unit cell. The atomic packing factor is
0.74 which means it has 26% void space per unit cell.
face-centered cubic (FCC) crystal structure
Two other important characteristics of a crystal structure
Coordination number
Atomic packing factor (APF)
For metals, each atom has the
same number of nearest-neighbour or touching atoms,
Coordination number
is the sum of the sphere
volumes of all atoms within a unit cell (assuming the atomic
hard-sphere model) divided by the unit cell volume
Atomic packing factor (APF)
The atomic packing factor is 0.68 which means it has 32%
void space per unit cell. Contain 2 atoms in a unit cell
BODY-CENTERED CUBIC (BCC)
The equivalent of 6 atoms is contained in each unit cell; one-sixth of each of the 12 top and bottom face corner atoms, one-half of each of the 2 center face atoms, and all 3 midplane interior atoms. The atomic packing
factor for HCP is 0.74 which means it has 26% void space per unit cell.
HEXAGONAL-CLOSE PACKED (HCP)