The Story of Chemistry Flashcards
History of chemical notation
Dalton began using symbols for atoms or elements. This was then simplified by Berzelius using the Latin names and assigning the meanings of super and subscripts. IUPAC in 1919
etymology
origin of words
Ordering the elements
As people discovered elements, they realised many elements had similar properties. Telluric screw was first proposed but was difficult to digest. Newlands came up with octaves. Then finally the periodic table by Mendeleev
Competition for the periodic table
Meyer and Mendeleev. Mendeleev better accounted for gaps in the table
CAS
Chemical Abstracts Service
Washing soda
Knew how to make soap from sea salt, but needed a large scale way of doing so to make it accessible. Leblanc came up with a method, but it produced large amounts of HCl.
Sucrose
Rillieux. Isolation from non-sugar cane products using a triple-effect evaporator. Was effective, but doubled sugar consumption in 25 years in Europe.
Clean drinking water
Edward Frankland. Stressed that appearance was not an indicator for water’s safety
Saccharin and cyclamate
Constantine Fahlberg. Discovered by accident due to a spillage on his hands. Cyclamate was discovered to counteract the bitter aftertaste of saccharin.
Saccharin and cancer
Studies on rats in the 70s linked saccharin to bladder cancer, it was banned in 1981. Human studies showed no consistent evidence and the ban was lifted in 2010
Discovery of caffeine
Runge had discovered another stimulant, was given a sample of coffee to see if a similar chemical component existed
MSG
Actively isolated from dashi. Not accidental etc
Mauveine
Discovered whilst trying to convert aniline into quinine.
Coca
Plant was used by native people of the Andes for millennia. Cocaine isolated in the 1860s in an attempt to isolate cocas benefits
DDT
First synthesized just as a chemical. Later synthesized in the search for an effective insecticide. Took 66 years
Haber
Generating ammonia from nitrogen in the air using less harsh conditions. Europe’s population had tripled in 200 years and needed to be fed. Also made chlorine gas for the war
Midgley
TEL and CFCs. Both ground breaking but ultimately devastating.