The rate of reaction Flashcards
what is needed for a chemical reaction to happen?
-reactant particles must collide with each other
-the particles must have enough energy for them to react
what is a successful collision?
A collision that produces a reaction
what is activation energy?
the minimum amount of energy needed for a collision to be successful
what are the units for rate? mass and volume
g/s or g/m
cm3/s or cm3/min.
what is the correlation between frequency and rate of reaction?
the greater the frequency of successful collisions, the greater the rate of reaction
what happens when the concentration or the pressure of a reacting gas is increased? (3)
-the reactant particles are closer together
-the frequency of collisions between reactant particles increases
-therefore the rate of reaction increases
what happens when a solid is grounded into powder? (3)
-its total volume stays the same
-the area of exposed surface increases
-the surface area to volume ratio increases
what happens when the surface area to volume ratio of a reacting solid is increased? (3)
-more reactant particles are exposed at the surface
-the frequency of collisions between reactant particles increases
-therefore the rate of reaction increases
what happens when the temperature for a reaction mixture is increased? (4)
-reactant particles move more quickly
-the energy of the particles increases
-the frequency of successful collisions between reactant particles increases
-therefore the rate of reaction increases
which 2 factors does increase in temperature contribute to?
frequency of collisions and energy of collisions
what do catalysts only affect? what do they NOT affect?
the rate of reaction - they do not affect the yield of the reaction.
how do catalysts work?
provides an alternative reaction pathway that has a lower activation energy than the uncatalysed reaction
what do catalysts NOT increase?
the frequency of collisions
what do catalysts increase the frequency of? why?
successful collisions because a greater proportion of collisions now exceeds this lower activation energy.
what does a reaction profile show?
the effect of a catalyst on activation energy