The Rate And Extent Of Chemical Change Flashcards

1
Q

What is the rate of reaction?

A

A MEASURE of HOW QUICKLY a REACTANT is USED UP or how quickly a PRODUCT is FORMED

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2
Q

What two things need to happen for a reaction to happen?

(Collision Theory)

**

A

-REACTANT particles MUST COLLIDE with EACHOTHER

-The particles must have ENOUGH ENERGY to REACT

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3
Q

What is a successful collision defined by?

**

A

A COLLISION that PRODUCES a REACTION

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4
Q

What is activation energy?

**

A

The MINIMUM AMOUNT of ENERGY needed for a COLLISION to be SUCCESSFUL

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5
Q

Why is activation energy different for different reactions?

A
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6
Q

Describe the three stages of chemical reaction according to Collision Theory

(BLURT QUESTION)

A
  1. TWO PAIRS of particles MOVE TOWARDS EACH OTHER
  2. The PAIRS COLLIDE and REFORM so that EACH MEMBER of the ORIGINAL PAIR JOINS with a MEMBER of the OTHER PAIR
  3. Two NEW PAIRS are FORMED and EACH PAIR MOVES AWAY from EACH OTHER
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7
Q

How do you calculate the mean rate of reaction?

**

A

-QUANTITY of REACTANT USED / TIME Taken

-QUANTITY of PRODUCT FORMED / TIME taken

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8
Q

Why is measuring mass important when a reaction forms carbon dioxide?

A

CARBON DIOXIDE is KNOWN to LEAVE the CONTAINER which AFFECTS RESULTS

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9
Q

Why is measuring mass not suitable for hydrogen?

A
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10
Q

What are the units for the rate of mass change?

**

A

G/s or G/min

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11
Q

When is measuring the change in volume useful?

**

A

When a GAS LEAVES a CONTAINER

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12
Q

How is the change in volume measured?

**

A

Using an UPSIDE-DOWN BURETTE or a MEASURING CYLINDER

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13
Q

What is an upside down burette?

A
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14
Q

Describe one way to measure volume change

(BLURT METHOD)

A
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15
Q

Describe a second way to measure volume change

(BLURT QUESTION)

A
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16
Q

What are the units for change in volume?

**

A

Cm^3 per s^-1 or cm^3 per min^-1

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17
Q

What kind of graph can the rate of reaction be plotted against?

A

A TOTAL MASS / VOLUME (Y-AXIS)
against TIME (X-AXIS) graph

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18
Q

What is the gradient of a volume/mass to time graph equal to?

A

The RATE of REACTION

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19
Q

What does the horizontal line tell you?

A

When the REACTION FINISHES

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20
Q

What does the steepness of the line tell you?

**

A

The STEEPER the LINE the GREATER the RATE of REACTION

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21
Q

What is until for rate of reaction?

A

Mol / s^-1

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22
Q

How do you calculate the mole?

**

A

Mass / Mr

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23
Q

How does the frequency of successful collisions affect the rate of reaction?

**

A

The GREATER the FREQUENCY of SUCCESSFUL COLLISIONS the GREATER the RATE of REACTION

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24
Q

How does increasing concentration or pressure affect the rate of reaction in a gas?

**

A

INCREASES the RATE of REACTION by making PARTICLES MORE CROWDED

25
What is mean energy? ***
The AVERAGE CAPACITY of a SYSTEM to DO WORK
26
Why does the mean energy of particles not change even though the rate of reaction increases? ***
27
What kind of graph can the total amounts of products be plotted against? **
A TOTAL MASS / VOLUME ( Y AXIS) against TIME (X AXIS) GRAPH
28
What is a tangent? ***
29
How do you draw the tangent? ***
30
Why do larger lumps have smaller surface to volume ratios than small lumps? ***
31
What happens to a large lump’s volume when it is divided or ground into powder? ***
It STAYS the SAME because VOLUME is just the MEASURE of the AMOUNT of SPACE its OBJECT can OCCUPY
32
What happens to the amount of exposed surface when a large lump is divided or ground into powder? ***
The AREA of EXPOSED SURFACE INCREASES
33
What happens to a the surface area to volume ratio of a large lump when it is divided or ground into powder? **
INCREASES
34
How does increasing the surface area to volume ratio affect the rate of reaction? (BLURT QUESTION) ***
-INCREASES the RATE of REACTION -The VOLUME STAYS the SAME -The AREA of EXPOSED SURFACE INCREASES -The SURFACE AREA to VOLUME RATIO INCREASES
35
How does temperate increase the energy of collisions? **
INCREASES the ENERGY of COLLISIONS
36
What is a catalyst? ***
A SUBSTANCE which INCREASES the RATE of REACTION. Its is NOT USED OP or CHEMICALLY CHANGED and it does NOT ALTER the PRODUCTS of the REACTION
37
Why doesn’t a catalyst change or “use up” during a reaction? ***
CATALYSTS only SPEND a SHORT AMOUNT of TIME with the CHEMICALS
38
Why is only a small mass of catalyst needed to increase the rate of reaction? (BLURT QUESTION) ***
CATALYSTS are NOT USED UP which means each MOLECULE can INTERACT with MANY MOLECULES CATALSYTS give the PARTICLES the ENERGY they NEED to INCREASE the RATE of REACT
39
Why do not all substances have suitable catalysts? *** (BLURT QUESTION)
40
What are some examples of different types of catalysts? *** (BLURT QUESTION)
-Enzymes -Hydrochloric Acid -Platinum
41
Why do different catalysts catalyse different reactions? *** (BLURT QUESTION)
DIFFERENT CATALYSTS have SPECIFIC PROPERTIES that MATCH the NEEDS of PARTICULAR REACTIONS
42
How does a catalyst lower activation energy?
A CATALYST PROVIDES an AN ALTERNATE REACTION REACTION PATHWAY that has a LOWER ACTIVATION ENERGY
43
How does the use of a catalyst affect the number of collisions? ***
Does NOT CHANGE the FREQUENCY of COLLISIONS however it does INCREASE the NUMBER of SUCCESSFUL COLLISIONS due to a LOWER ACTIVATION ENERGY
44
Describe the difference between the reaction profiles of a reactant with a catalyst and then without a catalyst?
The CURVE is SHORTER since the ACTIVATION ENERGY is LESS
45
What is a reversible reaction?
A CHEMICAL REACTION which SWINGS BOTH WAYS
46
Which direction does the arrow for a forward reaction point?
RIGHT
47
What direction do the arrows point for a backward reaction?
LEFT
48
How can the proportion of reactants and products be changed by altering reaction conditions?
Changing TEMP, PRESSURE or using CATALYSTS
49
What is an example of a reaction condition which would decrease the amount of reactants / products?
DECREASING the TEMPERATURE
50
What is an example of a reaction condition which would increase the amount of reactants/products?
INCREASING the TEMPERATURE
51
What happens during energy changes during a reversible reaction?
If a REACTION is EXOTHERMIC in ONE DIRECTION it will be ENDOTHERMIC in THE OTHER DIRECTION
52
What does ‘hydrated’ mean?
Containing WATER of CRYSTALLISATION
53
Describe the structure of copper sulfate
A CRYSTAL, IONIC LATTICE
54
How is water removed from copper sulfate?
HEAT
55
What is left behind after heating copper sulfate?
WHITE, ANHYDROUS COPPER SULFATE
56
What does anhydrous mean?
NOT HYDRATED or CONTAINING NO WATER
57
What type of reaction is the forwards reaction?
ENDOTHERMIC
58
What type of reaction is the backwards reaction?
EXOTHERMIC
59
What happens when you add water again to the heated solution of copper sulfate?
It’s REHYDRATED