The origin of colour in complexes Flashcards
the three main concepts to consider when explaining the colour of metal complexes are:
- the electromagnetic spectrum and the colour wheel
- the connection between colour, energy and wavelength
- the electronic configurations of transition metal ions
the electromagnetic spectrum is
the range of all wavelengths ans frequencies of all the types of radiation
complementary colours are
colours opposite each other on a colour wheel
visible light (‘white light’) is made up of
an infinite number of colours, not just seven !
when white light is passed through a solution containing a transition metal complex,
some wavelengths of light are absorbed by the complex
therefore, the emerging light will contain proportionately more of the complementary colour.
so if a complex absorbs red light, the light emerging will look blue or green
name the colours of these complexes: Ti2+ V3+ VO2+ Cr3+ Cr2O7 2- Mn2+ MnO4- Fe3+ Co2+ Ni2+ Cu2+
name the colours of these complexes: Ti2+ (red) V3+ (green) VO2+ (blue) Cr3+ (green) Cr2O7 2- (orange) Mn2+ (pink) MnO4- (purple) Fe3+ (yellow) Co2+ (red) Ni2+ (light blue) Cu2+ (blue)