Square planar complexes Flashcards

1
Q

a square planar shape contains

A

contains a central atom or ion surrounded by four atoms or ligands in the same plane and with bond angles of 90 degrees

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2
Q

an example of a square planar shape is

A

xenon tetrafluoride, XeF4

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3
Q
  • an atom of xenon has ……… electrons in its outermost energy level and each fluorine uses……………….to form a …………………..bond
  • the outer energy level now contains………..e-
  • the compound’s shape is………..because……………
A
  • 8 electrons in its outermost energy level
  • each fluorine atom uses one of its electrons to form a covalent bond
  • the outer energy level now contains 12 electrons arranged in six pairs, forming an octahedral shape, with two of the pairs being lone pairs
  • shape is square planar as the two lone pairs repel each other and are therefore located opposite each other, so the four bonding pairs are in a plane (flat, 2D), with the fluorine atoms at the corners of a square and an F-Xe-F bond angle of 90 degrees
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4
Q

cis-platin is used for

A

its effective treatment of some types of cancer, especially testicular cancer

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5
Q

the cis-platin and trans-platin has the formulae

A

[Pt(NH3)2(Cl)2]

in cis isomer, the identical ligands are next to each other while in trans, they are opposite each other

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6
Q

cis-platin prevents the spread of a cancer tumour by:

A
  • all cells contain deoxyribunucleic acid (DNA)
  • during cell division, DNA must separate
  • the structure of cis-platin allows it to form a bond between two strands of DNA, so preventing it from separating
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