The Halogens Flashcards

1
Q

What happens down the halogen group in terms of boiling point?

A

It increases

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2
Q

Explain the trend in boiling point down the halogen group

A

Id-Id or London forces increase so more energy is needed to overcome them

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3
Q

What happens down the halogen group in terms of reactivity with halide ions?

A

Decreases

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4
Q

Explain the trend in reactivity down the halogen group with halide ions

A

The added electron is further from the nucleus and it shielded by more electrons in inner shells so the electrostatic attraction decreases and so reactivity decreases

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5
Q

What are displacement reactions in terms of halogens?

A

Reactions in which a more reactive halogen will oxidise and displace a less reactive halogen from its salt

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6
Q

What can halogen solutions be added to, to produce displacement reactions?

A

NaCl
NaBr
NaI

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7
Q

What is the colour of chlorine in water?

A

Pale green

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8
Q

What is the colour of bromine in water?

A

Orange

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9
Q

What is the colour of iodine in water?

A

Brown

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10
Q

What is the colour of chlorine in cyclohexane?

A

Pale-green

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11
Q

What is the colour of bromine in cyclohexane?

A

Orange

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12
Q

What is the colour of idoine in cyclohexane?

A

Purple

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13
Q

What happens to show that a redox reaction has taken place with halogens reacting with halide ions?

A

A colour change

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14
Q

What is usually also added to the solution of halogen and sodium halide?

A

Usually shaken with cyclohexane to distinguish between bromine and iodine

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15
Q

Which halogen in the most reactive?

A

Chlorine

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16
Q

What is the colour change of halogens determined by?

A

The halogen in the solution - the most reactive halogen oxides the halide ions and so becomes the halide ions so the colour is determined by the halogen

17
Q

The equation of chlorine and water in water treatment

A

Cl2 + H2O ———-> HClO + HCl

18
Q

Equation of chlorine and sodium hydroxide and what it forms (specific ion)

A
Cl2 + 2NaOH ----------> NaCl + NaClO + H2O
Forms bleach (ClO-)
19
Q

What conditions are needed for when chlorine makes bleach

A

Reacts with cold, dilute aqueous NaOH

20
Q

Name 2 negatives for the chlorination of water

A

Cl’s toxicity means care has to be taken

Can react with organic matter to form chlorinated hydrocarbons which may be carcinogenic