The Final Chem 2B flash card reminder
Molality
Moles of solute/ mass of solvent
Molarity
moles of solvent or solute/volume (L)
When the question is asking for particular mole fraction of molecule above the solution we use…
XaVap = Pa/Ptot
Mass percent
Mass of solute/ Total mass of compound
Calculating boiling point
Change in Temperature: T(solution) + T(pure solution)
Freezing point
Change in temperature: T(pure-solvent) + (T solution)
Heat capacity equation
q= mCsp( change in Temperature)
London Dispersion forces
The less electronegativity the less polar the greater the London dispersion forces
Remember the higher EN: HF
Determining Volatility
- Lighter molar weight = higher volatility
- Non-polars have low intermolecular forces: high volatility 1
- Polar molecules have stronger intermolecular forces: meaning lower volatility
Dipole moment:
Large dipole moments determined by forces. Greatest to least forces
Ionic>dipole-dipole> Hydrogen bonds >London dispersion
Ionic bonding
between a metal and non metal
Cohesion and adhesive in hydrogen bonding
Cohesion water sticks to each other
Adehsive water molecules stick onto surfaces
MO diagram structure P orbitals
Anything from Oxygen to the left is 2,1,2,1
Anything from Oxygen to the right is 1,2,2,1
When to convert Celsius to Kelvin and when not to convert Celsius to Kelvin
when it includes R: Convert Celsius to Kelvin
When its Thermochem question like finding Q rxn just leave the temperature to celcieus C.
ppm
1/10^6